The synthesis, structure, and full characterization of a redox‐switchable germylene based on
a [3] ferrocenophane ligand arrangement,[Fc (NMes) 2Ge](4), is presented. The mesityl …

The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl thallium compound,[
TismPriBenz] Tl, reacts with Li, Na, K, and Rb to afford the respective alkali metal carbatrane …

Very high activities were observed in the redox-induced hydroamination of alkynes by
employing a redox-active gold (I) complex featuring an electron-deficient, terphenyl …

Abstract Hitherto unknown Au→ Al interactions have been evidenced upon coordination of
the geminal phosphorus–aluminum Lewis pair Mes2PC ( CHPh) AltBu2 (Mes= 2, 4, 6 …

The synthesis and characterisation of several metal complexes of a redox‐active, mesityl
(Mes)‐substituted [1] phosphaferrocenophane, FcPMes (1), are reported. Cyclic voltammetry …

The synthesis and full characterization of several transition metal complexes of a redox-
switchable, biaryl (ArT)-substituted [1] phosphaferrocenophane, FcPArT (L2), in conjunction …

The tris [(1-isopropylbenzimidazol-2-yl) dimethylsilyl] methyl ligand,[TismPriBenz], has been
employed to form carbatrane compounds of both the main group metals and transition …

The synthesis, characterisation and reactivity of new phosphine-functionalised tris
(pyrazolyl) methane ligands (TpmPR2, 2a–c, with R= Ph, nBu, iPr) are presented. The …

Azoles and poly (azoles), in their neutral or anionic forms, have emerged as potential
ligands during the past forty years and, due to their versatility, they still play a vital role in …

Three types of trivalent rare-earth-metal complexes supported by a monoanionic tris
(pyrazolyl) methanide ligand were synthesized and structurally characterized, and the …