Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
Kinetics of the Simplest Criegee Intermediate Reaction with Water Vapor: Revisit and Isotope Effect
YJ Wu, K Takahashi, JJM Lin - The Journal of Physical Chemistry …, 2023 - ACS Publications
The kinetics of the simplest Criegee intermediate (CH2OO) reaction with water vapor was
revisited. By improving the signal-to-noise ratio and the precision of water concentration, we …
revisited. By improving the signal-to-noise ratio and the precision of water concentration, we …
Molecular insights into the formation of Criegee intermediates from β-hydroxyperoxy radicals
L Chen, Y Huang, Y Xue, Z Jia - Atmospheric Environment, 2024 - Elsevier
Organic peroxy radicals (RO 2) and Criegee intermediates (CI, carbonyl oxides) are key
reactive species in atmospheric chemistry, and can proceed various reactions influencing …
reactive species in atmospheric chemistry, and can proceed various reactions influencing …
Long-wave mid-infrared time-resolved dual-comb spectroscopy of short-lived intermediates
PL Luo - Optics Letters, 2020 - opg.optica.org
In this Letter, an electro-optic dual-comb spectrometer with a central tunable range of 7.77–
8.22 µm is demonstrated to perform transient absorption spectroscopy of the simplest …
8.22 µm is demonstrated to perform transient absorption spectroscopy of the simplest …
Synchronized Two-Color Time-Resolved Dual-Comb Spectroscopy for Quantitative Detection of HOx Radicals Formed from Criegee Intermediates
Criegee intermediates, derived from ozonolysis of alkenes and recognized as key species in
the production of nonphotolytic free radicals, play a crucial role in atmospheric chemistry …
the production of nonphotolytic free radicals, play a crucial role in atmospheric chemistry …
Experimental and Computational Studies of Criegee Intermediate syn-CH3CHOO Reaction with Hydrogen Chloride
S Liu, X Zhou, Y Chen, Y Liu, S Yu… - The Journal of …, 2021 - ACS Publications
Hydrogen chloride (HCl) contributes substantially to the atmospheric Cl; both species could
affect the composition of Earth's atmosphere and the fate of pollutants. Here, we present the …
affect the composition of Earth's atmosphere and the fate of pollutants. Here, we present the …
Infrared Characterization of the Products of the Reaction between the Criegee Intermediate CH3CHOO and HCl
ZS Su, YP Lee - The Journal of Physical Chemistry A, 2023 - ACS Publications
The rapid reactions between Criegee intermediates and hydrogen halides play important
roles in atmospheric chemistry, particularly in the polluted urban atmosphere. Employing a …
roles in atmospheric chemistry, particularly in the polluted urban atmosphere. Employing a …
Detailed mechanism and kinetics of the reaction of Criegee intermediate CH 2 OO with HCOOH investigated via infrared identification of conformers of …
The reaction of Criegee intermediate CH2OO with HCOOH is important in atmospheric
chemistry, but its mechanism and kinetics are little investigated. We recorded time-resolved …
chemistry, but its mechanism and kinetics are little investigated. We recorded time-resolved …
Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH 2 OO and HCl
Reactions between Criegee intermediates and hydrogen halides might be significant,
particularly in the polluted urban atmosphere, because of their large rate coefficients …
particularly in the polluted urban atmosphere, because of their large rate coefficients …
Mechanism and kinetics of the reaction of the Criegee intermediate CH 2 OO with acetic acid studied using a step-scan Fourier-transform IR spectrometer
Acetic acid, CH3C (O) OH, plays an important role in the acidity of the troposphere. The
reactions of Criegee intermediates with CH3C (O) OH have been proposed to be a potential …
reactions of Criegee intermediates with CH3C (O) OH have been proposed to be a potential …