This review describes the effects of highly deformed porphyrin ring on the electronic
structures of iron (III) porphyrinates, which includes (i) the electron configurations in low-spin …

The electronic ground state of most known ferric heme proteins is either low-spin (S) 1/2) or
high-spin (S) 5/2). However, a small number of these proteins do not conform to this regime …

To determine the factors affecting the ground-state electron configuration of low-spin Fe (III)
porphyrin complexes, we have examined the 1H NMR, 13C NMR, and EPR spectra of a …

1H NMR, 13C NMR, and EPR spectra of six-coordinate ferric porphyrin complexes [Fe (Por)
L2] ClO4 with different porphyrin structures are presented, where porphyrins (Por) are planar …

The spin states of the iron (III) complexes with a highly ruffled porphyrin ring,[Fe (TEtPrP) X]
where X= F-, Cl-, Br-, I-, and ClO4-, have been examined by 1H NMR, 13C NMR, EPR, and …

Studies on the electronic and magnetic structures of iron (II), iron (III), and iron (IV) porphyrin
complexes and their radical cations are important for understanding aspects of the biological …

The electronic structures of six-coordinate iron (III) octaethylmonoazaporphyrins,[Fe (MAzP)
L2]±(1), have been examined by means of 1H NMR and EPR spectroscopy to reveal the …

The electronic states of a series of saddle-shaped porphyrin complexes [Fe (OMTPP) L2]+
and [Fe (TBTXP) L2]+ have been examined in solution by 1H NMR, 13C NMR, and EPR …

The spin states of microcrystalline samples of [Fe (OMTPP) L2]+(L= DMAP or Py) have been
examined and interpreted using Mössbauer spectroscopy, SQUID magnetometry and X-ray …

Highly saddle shaped (porphyrinato)iron( iii ) iodide with a pure intermediate spin state -
Chemical Communications (RSC Publishing) DOI:10.1039/B202768B Royal Society of …