Recent progress in cyclic aryliodonium chemistry: syntheses and applications

X Peng, A Rahim, W Peng, F Jiang, Z Gu… - Chemical …, 2023 - ACS Publications
Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

Recent advances in metal-catalyzed asymmetric 1, 4-conjugate addition (ACA) of nonorganometallic nucleophiles

K Zheng, X Liu, X Feng - Chemical reviews, 2018 - ACS Publications
The metal-catalyzed asymmetric conjugate addition (ACA) reaction has emerged as a
general and powerful approach for the construction of optically active compounds and is …

IDPi catalysis

L Schreyer, R Properzi, B List - … Chemie International Edition, 2019 - Wiley Online Library
High acidity and structural confinement are pivotal elements in asymmetric acid catalysis.
The recently introduced imidodiphosphorimidate (IDPi) Brønsted acids have met with …

Access to chiral β-sulfonyl carbonyl compounds via photoinduced organocatalytic asymmetric radical sulfonylation with sulfur dioxide

FS He, C Zhang, M Jiang, L Lou, J Wu, S Ye - Chemical Science, 2022 - pubs.rsc.org
An organocatalytic enantioselective radical reaction of potassium alkyltrifluoroborates,
DABCO·(SO2) 2 and α, β-unsaturated carbonyl compounds under photoinduced conditions …

Enantioselective intermolecular Pd-catalyzed hydroalkylation of acyclic 1, 3-dienes with activated pronucleophiles

NJ Adamson, KCE Wilbur… - Journal of the American …, 2018 - ACS Publications
We report a highly enantioselective Pd–PHOX-catalyzed intermolecular hydroalkylation of
acyclic 1, 3-dienes. Meldrum's acid derivatives and other activated C-pronucleophiles, such …

Asymmetric three-component reaction to assemble the acyclic all-carbon quaternary stereocenter via visible light and phosphoric acid catalysis

ZW Qiu, L Long, ZQ Zhu, HF Liu, HP Pan, AJ Ma… - ACS …, 2022 - ACS Publications
Chiral acyclic all-carbon quaternary stereocenters are widely present in natural products
and pharmaceuticals. However, their introduction remains a challenging topic in the …

Recent advances in the catalytic applications of chiral schiff‐base ligands and metal complexes in asymmetric organic transformations

S De, A Jain, P Barman - ChemistrySelect, 2022 - Wiley Online Library
The Schiff base and its metal complexes are extensively studied for their adaptable metal
chelating properties. Their ability to alter the design and modify it for various organic and …

Calix [n] arenes and its derivatives as organocatalysts

G Sachdeva, D Vaya, CM Srivastava, A Kumar… - Coordination Chemistry …, 2022 - Elsevier
Small organic compounds that replicate the actions of enzymes and inorganic catalysts are
known as organocatalysts. They have the benefit of being inexpensive, less toxic, and …

Construction of all-carbon quaternary stereocenters by catalytic asymmetric conjugate addition to cyclic enones in natural product synthesis

Z Wang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Asymmetric catalysis for chiral compound synthesis is a rapidly growing field in modern
organic chemistry and provides enantioselective materials to meet the demands of various …

Catalytic asymmetric synthesis of spiropyrazolones and their application in medicinal chemistry

X Xie, L Xiang, C Peng, B Han - The Chemical Record, 2019 - Wiley Online Library
Chiral spiropyrazolones are unique frameworks widely found in a large family of medicinally
relevant compounds with various biological activities. Substantial research efforts have been …