In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

The scarcity of precious metals has led to the development of sustainable strategies for
metal‐catalyzed cross‐coupling reactions. The establishment of new catalytic methods …

Despite the success of Sonogashira coupling for the synthesis of arylalkynes and
conjugated enynes, the engagement of unactivated alkyl halides in such reactions remains …

Complete control of the product of a catalytic reaction can be achieved on the basis of
catalyst structure, even when the reaction conditions are nearly identical. Catalyst‐controlled …

A new α‐C (sp3) H alkynylation of unactivated tertiary aliphatic amines with 1‐iodoalkynes
as radical alkynylating reagents in the presence of [Au2 (μ‐dppm) 2] 2+ in sunlight provides …

C (sp3)–C (sp) bond formations are of immense interest in chemistry and material sciences.
We report herein a convenient, radical-mediated and catalytic method for C (sp3)–C (sp) …

The first iron-catalyzed enantioselective cross-coupling reaction between an organometallic
compound and an organic electrophile is reported. Synthetically versatile racemic α-chloro …

Many nickel-based catalysts have been reported for cross-coupling reactions of
nonactivated alkyl halides. The mechanistic understanding of these reactions is still …