Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2019
JH Farnaby, T Chowdhury, SJ Horsewill… - Coordination Chemistry …, 2021 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2019.
Organo-f-element chemistry, including Sc, Y, the lanthanides and the actinides, has been a …
Organo-f-element chemistry, including Sc, Y, the lanthanides and the actinides, has been a …
Isolation and redox reactivity of cerium complexes in four redox states
The chemistry of lanthanides is limited to one electron transfer reactions due to the difficulty
of accessing multiple oxidation states. Here we report that a redox-active ligand combining …
of accessing multiple oxidation states. Here we report that a redox-active ligand combining …
Synthesis, Characterization, and Reduction of Thorium Pyridinediimine Complexes
A family of thorium complexes featuring the redox-noninnocent pyridinediimine ligand
MesPDIMe was synthesized, including (MesPDIMe) ThCl4 (1-Th),(MesPDIMe) ThCl3 …
MesPDIMe was synthesized, including (MesPDIMe) ThCl4 (1-Th),(MesPDIMe) ThCl3 …
Metal–Ligand Redox Cooperativity in Cerium Amine-/Amido-Phenolate-Type Complexes
C Uruburo, DMR YP Rupasinghe, H Gupta… - Inorganic …, 2023 - ACS Publications
The synthesis and characterization of two cerium complexes of redox-active amine/amido-
phenolate-type ligands are reported. A tripodal framework comprising the tris (2-(3′, 5′-di …
phenolate-type ligands are reported. A tripodal framework comprising the tris (2-(3′, 5′-di …
Neodymium based acylpyrazolone complexes: Synthesis and physicochemical characterizations
The electronic spectra of three neodymium acylpyrazolone complexes with the compositions
[Nd (DMBPMP) 3 (H 2 O)(EtOH)](Nd1),[Nd (DMMCPMP) 3 (H 2 O)(EtOH)](Nd2), and [Nd …
[Nd (DMBPMP) 3 (H 2 O)(EtOH)](Nd1),[Nd (DMMCPMP) 3 (H 2 O)(EtOH)](Nd2), and [Nd …
Synthesis of LnII‐in‐Cryptand Complexes by Chemical Reduction of LnIII‐in‐Cryptand Precursors: Isolation of a NdII‐in‐Cryptand Complex
Lanthanide triflates have been used to incorporate NdIII and SmIII ions into the 2.2. 2‐
cryptand ligand (crypt) to explore their reductive chemistry. The Ln (OTf) 3 complexes (Ln …
cryptand ligand (crypt) to explore their reductive chemistry. The Ln (OTf) 3 complexes (Ln …
Carbon Dioxide Reduction by Multimetallic Uranium (IV) Complexes Supported by Redox-Active Schiff Base Ligands
The synthesis, structure, and reactivity with CO2 and CS2 of new U (IV) complexes with a
redox-active Schiff base are reported. The reaction of UI3 with the heptadentate Schiff base …
redox-active Schiff base are reported. The reaction of UI3 with the heptadentate Schiff base …
Synthesis and characterization of borohydride rare-earth complexes supported by 2-pyridinemethanamido ligands and their application in the ring-opening …
M Beauvois, F Capet, JQ Nguyen, JW Ziller… - Dalton …, 2025 - pubs.rsc.org
The synthesis of 2-pyridinemethanamido borohydride complexes of yttrium and neodymium
was achieved through the in situ deprotonation of the protio-ligand 2-pyridinemethanamine …
was achieved through the in situ deprotonation of the protio-ligand 2-pyridinemethanamine …
Structural Features, Emission Analysis, and Covalency Comparison of Neodymium Acylpyrazolone Complexes using Oscillator Strengths, Covalency and Judd‐Ofelt …
Three distorted square antiprismatic eight coordinated neodymium acylpyrazolone
complexes were synthesized having the compositions [Nd (L1) 3 (H2O)(EtOH)](NdL1),[Nd …
complexes were synthesized having the compositions [Nd (L1) 3 (H2O)(EtOH)](NdL1),[Nd …
Diiminepyridine‐Supported Phosphorus (I) and Phosphorus (III) Complexes: Synthesis, Characterization, and Electrochemistry
Diiminepyridines (DIP) are popular redox “non‐innocent” ligands with widespread
application in late, first‐row transition metal mediated catalysis and coordination chemistry …
application in late, first‐row transition metal mediated catalysis and coordination chemistry …