1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

From the group of heterocyclic compounds, benzimidazoles remain the central focus, which
owns the important features as six-five member attached rings having two nitrogen atoms at …

A highly selective CuII‐catalyzed cross‐dehydrogenative ortho‐aminomethylation of
phenols with aniline derivatives is described. The corresponding C (sp2)− C (sp3) coupling …

C–H bond sulfonylation of anilines with the insertion of sulfur dioxide under metal-free
conditions is described. 2-Sulfonylanilines are generated in moderate to good yields …

Herein, we describe an intramolecular reductive aminocarbonylation of haloaryl-tethered
nitroarenes with carbon monoxide to access dibenzazepine-based heterocycles. The use of …

Herein, a highly exothermic primary amine–polyvalent iodine reaction has been used
successfully for selective functionalization of acidic C (sp3)–H groups for a dehydrogenative …

An efficient methodology is reported for the regioselective C-6 arylation of protected uracil
via the palladium catalyzed Csingle bondH functionalization of 1-(4-methoxybenzyl)-3 …

An I (III)-catalyzed oxidative cyclization reaction using selectfluor as the oxidant was
developed that converts ortho-substituted anilines to benzimidazoles. The mild reaction …

The development of an efficient process that produces bioactive medium‐sized N‐
heterocyclic scaffolds from 2‐substituted anilines using either iodosobenzene or (bis …