Polyelectrolyte complex coacervates: Recent developments and new frontiers

AM Rumyantsev, NE Jackson… - Annual Review of …, 2021 - annualreviews.org
Polyelectrolyte complex coacervates represent a wide class of materials with applications
ranging from coatings and adhesives to pharmaceutical technologies. They also underpin …

A comprehensive review of the structures and properties of ionic polymeric materials

JE Potaufeux, J Odent, D Notta-Cuvier, F Lauro… - Polymer …, 2020 - pubs.rsc.org
Dynamic materials, which include ionic polymeric materials, contain specific bonds or
interactions that can reversibly break and reform under certain stimuli or conditions. Among …

Effects of non-electrostatic intermolecular interactions on the phase behavior of pH-sensitive polyelectrolyte complexes

L Li, S Srivastava, S Meng, JM Ting, MV Tirrell - Macromolecules, 2020 - ACS Publications
Polyelectrolyte complexes (PECs) offer enormous material tunability and desirable
functionalities, and consequently have found broad utility in biomedical and material …

Kinetically Controlled and Nonequilibrium Assembly of Block Copolymers in Solution

SDP Fielden - Journal of the American Chemical Society, 2024 - ACS Publications
Covalent polymers are versatile macromolecules that have found widespread use in society.
Contemporary methods of polymerization have made it possible to construct sequence …

Advances in the structural design of polyelectrolyte complex micelles

AE Marras, JM Ting, KC Stevens… - The Journal of Physical …, 2021 - ACS Publications
Polyelectrolyte complex micelles (PCMs) are a unique class of self-assembled nanoparticles
that form with a core of associated polycations and polyanions, microphase-separated from …

Solid-to-liquid phase transition in polyelectrolyte complexes

S Meng, JM Ting, H Wu, MV Tirrell - Macromolecules, 2020 - ACS Publications
Strongly interacting polyelectrolyte complexes (PECs) are known to form solid precipitates
that can transform into liquid droplets upon the addition of salt to break intrinsic ionic …

Structural dynamics, phase behavior, and applications of polyelectrolyte complex micelles

S Shah, L Leon - Current Opinion in Colloid & Interface Science, 2021 - Elsevier
Self-assembly between oppositely charged polyelectrolytes conjugated to neutral polymeric
blocks form polyelectrolyte complex (PEC) micelles. These nanostructures have gained …

[HTML][HTML] Micro-to macro-phase separation transition in sequence-defined coacervates

CE Sing - The Journal of Chemical Physics, 2020 - pubs.aip.org
Phase separation can be driven by the association of oppositely charged polyelectrolytes in
solution, a process known as complex coacervation. This can manifest as macrophase …

Polyelectrolyte complexation of oligonucleotides by charged hydrophobic—neutral hydrophilic block copolymers

AE Marras, JR Vieregg, JM Ting, JD Rubien, MV Tirrell - Polymers, 2019 - mdpi.com
Polyelectrolyte complex micelles (PCMs, core-shell nanoparticles formed by complexation of
a polyelectrolyte with a polyelectrolyte-hydrophilic neutral block copolymer) offer a solution …

Effect of mixed solvents on polyelectrolyte complexes with salt

S Meng, Y Liu, J Yeo, JM Ting, MV Tirrell - Colloid and Polymer Science, 2020 - Springer
Strongly interacting polyelectrolyte complexes (PECs) are a versatile class of materials
whose physical states can be driven from solids into liquids and ultimately into homogenous …