Close contacts involving germanium and tin in crystal structures: Experimental evidence of tetrel bonds

P Scilabra, V Kumar, M Ursini, G Resnati - Journal of molecular modeling, 2018 - Springer
Modeling indicates the presence of a region of low electronic density (a “σ-hole”) on group
14 elements, and this offers an explanation for the ability of these elements to act as …

Modern organometallic multidentate ligand design strategies: The birth of the privileged “pincer” ligand platform

PA Chase, RA Gossage, G van Koten - The privileged pincer-metal …, 2016 - Springer
The seemingly simple tridentate ligand design, one that is now known as the “pincer,” has
gained increasing importance in metal–ligand chemistry and in other applications as diverse …

Self-assembly of extended Schiff base amino acetate skeletons, 2-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)] amino} phenylpropionate and 2-{[(E)-1-(2-hydroxyaryl) …

TSB Baul, C Masharing, G Ruisi, R Jirásko… - Journal of …, 2007 - Elsevier
The organotin (IV) compounds,[Ph3SnL1H] n· nCCl4 (1),[Me2SnL2 (OH2)](2),[nBu2SnL2](3)
,[Ph2SnL2] n (4),[Ph3SnL2H] n (5) and [Ph3SnL3H] n (7)(L1= 2-{[(2Z)-(3-hydroxy-1-methyl-2 …

Boranes with ultra-high stokes shift fluorescence

SJ Cassidy, I Brettell-Adams, LE McNamara… - …, 2018 - ACS Publications
The synthesis and optical characterization of 9-(2, 6-bis (methoxymethyl) phenyl)
borafluorene (BMMP-BF) are reported. NMR spectroscopic data and single-crystal X-ray …

Synthesis, structural characterization and in vitro antiproliferative effects of novel organotin (iv) compounds with nicotinate and isonicotinate moieties on carcinoma …

SM Vieriu, AA Someşan, C Silvestru… - New Journal of …, 2021 - pubs.rsc.org
In recent decades, organotin (IV) chemistry has seen a rapid growth owing to the biological,
pharmaceutical and medicinal applications found for different compounds. The aim of this …

Synthesis, characterization and crystal structures of polymeric and dimeric triphenyltin (IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl] …

TSB Baul, KS Singh, M Holčapek, R Jirásko… - Journal of …, 2005 - Elsevier
The triphenyltin (IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-
diazenyl] phenyl} methylidene) amino] aryls (aryls= 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been …

Self-assembly of diorganotin (IV) 2-{[(E)-1-(2-oxyaryl) alkylidene] amino} acetates: An investigation of structures by X-ray diffraction, solution and solid-state tin NMR …

TSB Baul, C Masharing, R Willem, M Biesemans… - Journal of …, 2005 - Elsevier
The diorganotin (IV) compounds,[Me2SnL2 (OH2)] 2 (1),[nBu2SnL2 (OH2)] 2 (2),[nBu2SnL1]
3· 0.5 C3H6O (3),[nBu2SnL3] 3· 0.5 C6H6 (4) and [Ph2SnL3] n· 0.5 C6H6 (5)(L= carboxylic …

Hypercoordinate compounds of the group 14 elements containing κn-C, N-, C, O-, C, S-and C, P-ligands

A Khan, D Foucher - Coordination Chemistry Reviews, 2016 - Elsevier
This review surveys recent developments in the field of pentacoordinated group 14 (ie, Si,
Ge, Sn, Pb) small molecules, and more specifically Sn compounds, containing ligands with …

OCO and NCO chelated derivatives of heavier group 15 elements. Study on possibility of cyclization reaction via intramolecular ether bond cleavage

L Dostál, R Jambor, A Růžička, R Jirásko… - Dalton …, 2011 - pubs.rsc.org
A set of four pincer ligands, either the OCO type ligands L1–3 [2, 6-(ROCH2) 2C6H3]−,
where R= Me (L1), mesityl (L2), t-Bu (L3) or novel NCO ligand [2-(Me2NCH2)-6-(t-BuOCH2) …

Intramolecular Chalcogen−Tin Interactions in (o-MeE-C6H4)CH2SnPh3-nCln (E = S, O; n = 0, 1, 2), Characterized by X-ray Diffraction and 119Sn …

T Munguia, M Lopez-Cardoso… - Inorganic …, 2007 - ACS Publications
Organotin (IV) compounds of the type (o-MeE-C6H4) CH2SnPh3-n Cl n were synthesized,
E= O, n= 0 (1), n= 1 (2), n= 2 (3) and E= S, n= 0 (4), n= 1 (5), n= 2 (6). The complexes exhibit …