Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Enzymatic late‐stage modifications: better late than never

E Romero, BS Jones, BN Hogg… - Angewandte Chemie …, 2021 - Wiley Online Library
Enzyme catalysis is gaining increasing importance in synthetic chemistry. Nowadays, the
growing number of biocatalysts accessible by means of bioinformatics and enzyme …

Cofactor NAD (P) H regeneration inspired by heterogeneous pathways

X Wang, T Saba, HHP Yiu, RF Howe, JA Anderson… - Chem, 2017 - cell.com
Biocatalysis can empower chemical, pharmaceutical, and energy industries, where the use
of enzymes facilitates low-energy, sustainable methods of producing high-value chemicals …

From protein film electrochemistry to nanoconfined enzyme cascades and the electrochemical leaf

FA Armstrong, B Cheng, RA Herold… - Chemical …, 2022 - ACS Publications
Protein film electrochemistry (PFE) has given unrivalled insight into the properties of redox
proteins and many electron-transferring enzymes, allowing investigations of otherwise ill …

Carbon dots as versatile photosensitizers for solar-driven catalysis with redox enzymes

GAM Hutton, B Reuillard, BCM Martindale… - Journal of the …, 2016 - ACS Publications
Light-driven enzymatic catalysis is enabled by the productive coupling of a protein to a
photosensitizer. Photosensitizers used in such hybrid systems are typically costly, toxic …

Efficient NADH regeneration by a redox polymer-immobilized enzymatic system

M Yuan, MJ Kummer, RD Milton, T Quah… - ACS …, 2019 - ACS Publications
Given the high costs and stoichiometric amounts of reduced nicotinamide adenine
dinucleotide (NADH) required by the many oxidoreductases used for organic synthesis and …

Selective hydrogenation of nitro compounds to amines by coupled redox reactions over a heterogeneous biocatalyst

D Sokolova, TC Lurshay, JS Rowbotham… - Nature …, 2024 - nature.com
Cleaner synthesis of amines remains a key challenge in organic chemistry because of their
prevalence in pharmaceuticals, agrochemicals and synthetic building blocks. Here, we …

Bringing biocatalytic deuteration into the toolbox of asymmetric isotopic labelling techniques

JS Rowbotham, MA Ramirez, O Lenz… - Nature …, 2020 - nature.com
Enzymes dependent on nicotinamide cofactors are important components of the expanding
range of asymmetric synthetic techniques. New challenges in asymmetric catalysis are …

Heterogeneous catalysis mediated cofactor NADH regeneration for enzymatic reduction

X Wang, HHP Yiu - ACS Catalysis, 2016 - ACS Publications
Enzymatic reduction using oxidoreductases is important in commercial chemical production.
This enzymatic action requires a cofactor (eg, NADH) as a hydrogen source that is …

Bioelectrocatalytic Cofactor Regeneration Coupled to CO2 Fixation in a Redox‐Active Hydrogel for Stereoselective C−C Bond Formation

L Castañeda‐Losada, D Adam… - Angewandte Chemie …, 2021 - Wiley Online Library
The sustainable capture and conversion of carbon dioxide (CO2) is key to achieving a
circular carbon economy. Bioelectrocatalysis, which aims at using renewable energies to …