Recent developments in catalytic asymmetric aldol reactions have been summarized.
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …

Catalytic decarboxylative reactions are attractive as biomimetic reactions and
environmentally friendly reaction processes. In this review, the origin and recent …

Catalytic asymmetric transformation is a powerful strategy for the introduction of chirality to
synthesize diverse nonracemic molecular entities. Chiral molecules play a significant role in …

This review examines recent advances in asymmetric catalytic decarboxylative addition
reactions which have become a powerful method to form C C and C X bond using …

The decarboxylative Mannich reaction (DMR) of β-ketoacids with imines has emerged as a
very important tool for the synthesis of natural products and biologically active compounds …

The first phosphine‐catalyzed enantioselective γ‐addition with prochiral nucleophiles and 2,
3‐butadienoates as the reaction partners has been developed. Both 3‐alkyl‐and 3‐aryl …

A rhodium-catalyzed chemo-and regioselective intermolecular decarboxylative addition of β-
ketoacids to terminal allenes is reported. Using a Rh (I)/DPPF system, tertiary and …

A novel Cu-catalyzed enantioselective decarboxylative Mannich reaction of cyclic aldimines
with β-ketoacids is described. The cyclic structure of these aldimines, in which the C N …

A newly prepared chiral-at-metal Rh (III) complex-catalyzed, highly efficient enantioselective
decarboxylative Michael addition of β-keto acids with α, β-unsaturated 2-acyl imidazoles or …

Disubstituted oxindoles with a stereogenic quaternary carbon center exist widely in various
natural products and biologically active compounds. Various strategies have been …