In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

Iron is the most abundant transition metal in Earth, s crust; it is relatively inexpensive, not
very toxic, and environmentally benign. 1 Undoubtedly, due to the involvement in a multitude …

Transition metal complexes play a vital role as catalysts in organic syntheses, enhancing
selectivity and rates of many transformations. Typically iron is not the first choice when it …

Although iron has been known and widely used in coordination and organometallic
chemistry for decades and N‐heterocyclic carbenes (NHCs) have also been used for about …

A Simple and Highly Efficient Iron Catalyst for a [2+2+2] Cycloaddition to Form Pyridines ×
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Heterocycles constitute one of the most interesting divisions of organic chemistry. A majority
of the compounds produced by nature as well as significant numbers of compounds …

Hydrosilylation with well defined piano‐stool iron (II) complexes bearing both N‐heterocyclic
carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones …

An iron-catalyzed [2+ 2+ 2] cycloaddition reaction of diynes and cyanamides at room
temperature is reported. Highly substituted 2-aminopyridines were obtained in good to …