Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials
FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …
and applications of metal complexes containing heteroallylic ligands such as amidinates …
Recent developments in highly basic N-heterocyclic iminato ligands in actinide chemistry
In the last decade, major conceptual advances in the chemistry of actinide molecules and
materials have been made to demonstrate their distinct reactivity profiles as compared to …
materials have been made to demonstrate their distinct reactivity profiles as compared to …
Hybrid amidinates and guanidinates of main group metals
T Chlupatý, A Růžička - Coordination Chemistry Reviews, 2016 - Elsevier
Complexes of main group metals containing amidinate and guanidinate ligands with an
additional functional/donor group are reviewed. Amino-, imino-, amido-, alkoxy-, phenoxy …
additional functional/donor group are reviewed. Amino-, imino-, amido-, alkoxy-, phenoxy …
Actinide‐Mediated Catalytic Addition of E H Bonds (E= N, P, S) to Carbodiimides, Isocyanates, and Isothiocyanates
Unprecedented catalytic reactivity of actinide coordination complexes toward
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
heterocumulenes, such as carbodiimides, isocyanates, and isothiocyanates is reported. The …
Mono (imidazolin-2-iminato) actinide complexes: synthesis and application in the catalytic dimerization of aldehydes
The synthesis of the mono (imidazolin-2-iminato) actinide (IV) complexes [(ImRN) An (N
{SiMe3) 2} 3](3–8) was accomplished by the protonolysis reaction between the respective …
{SiMe3) 2} 3](3–8) was accomplished by the protonolysis reaction between the respective …
Actinide-catalyzed intermolecular addition of alcohols to carbodiimides
The unprecedented actinide-catalyzed addition of alcohols to carbodiimides is presented.
This represents a rare example of thorium-catalyzed transformations of an alcoholic …
This represents a rare example of thorium-catalyzed transformations of an alcoholic …
Uranium (III) Redox Chemistry Assisted by a Hemilabile Bis (phenolate) Cyclam Ligand: Uranium–Nitrogen Multiple Bond Formation Comprising a trans-{RN U (VI) …
A new monoiodide U (III) complex anchored on a hexadentate dianionic 1, 4, 8, 11-
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …
Phosphorano-Stabilized Carbene Complexes with Short Thorium (IV)–and Uranium (IV)–Carbon Bonds
P Rungthanaphatsophon, P Huang… - Organometallics, 2018 - ACS Publications
While no alkylidene complexes of the f elements are known, the use of phosphorano-
stabilized carbene complexes to produce short actinide–carbon bonds has been previously …
stabilized carbene complexes to produce short actinide–carbon bonds has been previously …
Mixed imidazolin-2-iminato–Cp* thorium (IV) complexes: Synthesis and reactivity toward oxygen-containing substrates
The mixed pentamethylcyclopentadienyl thorium (IV) imidazolin-2-iminato complexes Cp*
2Th (ImDippN)(Me)(2) and Cp* 2Th (ImMesN)(Me)(3) were synthesized in quantitative yields …
2Th (ImDippN)(Me)(2) and Cp* 2Th (ImMesN)(Me)(3) were synthesized in quantitative yields …
Dithio-and diselenophosphinate thorium (IV) and uranium (IV) complexes: molecular and electronic structures, spectroscopy, and transmetalation reactivity
AC Behrle, A Kerridge, JR Walensky - Inorganic Chemistry, 2015 - ACS Publications
We report a comparison of the molecular and electronic structures of dithio-and
diselenophosphinate,(E2PR2) 1–(E= S, Se; R= i Pr, t Bu), with thorium (IV) and uranium (IV) …
diselenophosphinate,(E2PR2) 1–(E= S, Se; R= i Pr, t Bu), with thorium (IV) and uranium (IV) …