The hardness of oxo ions (O2−) means that coinage‐metal (Cu, Ag, Au) clusters supported
by oxo ions (O2−) are rare. Herein, a novel μ4‐oxo supported all‐alkynyl‐protected silver (I) …

Gold clusters have attracted great interest for a long time, and homo and heterometallic gold
clusters with hypercoordinated carbon are particularly interesting. This is due to their novel …

The first methodology for Au (I/III)-catalyzed oxidative cross-coupling of arenes via double C–
H activation has been developed. The reaction is fully selective for the cross-coupling …

Medicinal applications of gold complexes have recently attracted attention due to their
innovative antitumor mechanisms. In this work, two hypercoordinated carbon-centered gold …

A decanuclear gold (I)–sulfido complex,[(LH) 4Au10S4] Cl2 (LH-Au10S4-Cl, where LH= 4, 5-
bis (diphenylphosphanyl)-2 H-1, 2, 3-triazole), assembled from the reaction of H2S with the …

Due to the ubiquity of chirality in nature, chiral self‐assembly involving self‐sorting
behaviors has remained as one of the most important research topics of interests. Herein …

We report on the discovery of the first two examples of cationic palladium (II)‐oxo clusters
(POCs) containing f‐metal ions,[PdII6O12M8 {(CH3) 2AsO2} 16 (H2O) 8] 4+(M= CeIV, ThIV) …

By employing chiral precursors, a new class of chiral gold (I)–sulfido clusters with unique
structures has been constructed. Interestingly, pure enantiomers of the precursors are found …

While there is a growing interest in harnessing synergistic effects of more than one metal in
catalysis, relatively little is known beyond bimetallic systems. This report describes the …

Anions have been used to regulate the structures and luminescence of heterometallic
clusters. Introducing ClO4− into orange‐emissive, butterfly‐like [(C)(Au‐PPhpy2) 6Ag4](BF4) …