The Fe (IV) O (ferryl) moiety plays a crucial role in a variety of biological processes involved
in the production and storage of chemical energy, including aerobic respiration and …

High-valent Fe (IV)–oxo intermediates, found in enzyme active sites, are excellent targets for
biomimetic design of molecular catalysts for C–H bond activation. C–H bonds in inert …

Reported are the synthesis and detailed studies of the iron (IV)-tosylimido complexes of two
isomeric pentadentate bispidine ligands (bispidines are 3, 7-diazabicyclo [3.3. 1] nonane …

We study the oxidation of mononuclear Fe (II) centers in the metal–organic framework MOF-
74 in the presence of nitric oxide (NO), nitrogen dioxide (NO2), nitrous oxide (N2O), dinitrous …

Nickel-based catalysts are employed in organometallic transformations such as C–C/C–
heteroatom cross-coupling reactions. The work presented here describes the reactivity of …

In the past few decades, the mechanistic features of various first‐row transition metal‐oxo
dependent metalloenzymes and their biomimic models have been explored using various …

Computational catalysis is an ever-growing field, thanks in part to the incredible progression
of computational power and the efficiency offered by our current methodologies …