Nucleation dependence of atomic layer deposition on diamond surface termination

JC Jones, N Delegan, FJ Heremans, ABF Martinson - Carbon, 2023 - Elsevier
Surface termination and interfacial interactions are critical for advanced solid-state quantum
applications. In this paper, we demonstrate that atomic layer deposition (ALD) can both …

Site-Selective Atomic Layer Deposition at Thermally Generated Surface Oxygen Vacancies on Rutile TiO2

JC Jones, EP Kamphaus, JR Guest… - Chemistry of …, 2023 - ACS Publications
Unique atomic arrangements (ie, defects) on material surfaces may exhibit distinctive
reactivity that affords opportunities for selective surface chemistry exclusively at those sites …

Anatase TiO2 Surface Hydration: Infrared Vibrational Assignment and Facet-Specific Stability

C Luo, ZD Hood, ABF Martinson… - The Journal of Physical …, 2024 - ACS Publications
Anatase TiO2 nanoparticles support a subtle diversity of surface aqua and hydroxy
coordination environments that are characteristic of distinct facets and defect sites. The …

Site-Selective Atomic Layer Deposition on Rutile TiO2: Selective Hydration as a Route to Target Point Defects

EP Kamphaus, JC Jones, N Shan… - The Journal of …, 2023 - ACS Publications
Routes to area-and especially site-selective atomic layer deposition (ALD) remain an
enticing challenge in precision surface science, despite the potentially game-changing …

Tunable optical response of plasmonic metal oxide nanocrystals

BJ Roman, SA Shubert-Zuleta, DJ Milliron - MRS Bulletin, 2024 - Springer
This article is based on the MRS Medal presentation given by Delia J. Milliron at the 2023
MRS Fall Meeting & Exhibit in Boston, Mass. Milliron is cited “for the development of optically …

Resolving the Heat Generated from ZrO2 Atomic Layer Deposition Surface Reactions

AR Bielinski, EP Kamphaus, L Cheng… - Angewandte Chemie …, 2023 - Wiley Online Library
In situ pyroelectric calorimetry and spectroscopic ellipsometry were used to investigate
surface reactions in atomic layer deposition (ALD) of zirconium oxide (ZrO2). Calibrated and …

Theoretical Design Strategies for Area-Selective Atomic Layer Deposition

M Kim, J Kim, S Kwon, SH Lee, H Eom… - Chemistry of …, 2024 - ACS Publications
Area-selective atomic layer deposition (AS-ALD) is a bottom-up fabrication technique that
may revolutionize the semiconductor manufacturing process. Because the efficiency and …

Facet-enhanced dielectric sensitivity in plasmonic metal oxide nanocubes

BJ Roman, SA Shubert-Zuleta, G Shim… - The Journal of …, 2023 - ACS Publications
The resonant frequency of plasmonic nanoparticles depends on the refractive index of the
local environment, a property which is directly useful for sensing applications and is …

Mechanistically Informed Strategies for Site-Selective Atomic Layer Deposition

JC Jones, EP Kamphaus, L Cheng, C Liu… - Chemistry of …, 2024 - ACS Publications
While atomic layer deposition (ALD) processes from across the periodic table have been
designed to deposit conformal thin films, an atomistic view of disparate substrate sites …

Surface Dynamics of Selective Hydration of Rutile TiO2: A Kinetic Monte Carlo Approach

EP Kamphaus, JC Jones, J Xu, JR Guest… - The Journal of …, 2024 - ACS Publications
The utility of atomic layer deposition (ALD) continues to expand beyond conformal thin-film
fabrication to include area-or site-selective ALD. We previously identified a strategy for site …