Efficient and reliable amplification of chirality has borne its greatest fruit with transition metal-
catalyzed reactions since enantiocontrol may often be imposed by replacing an achiral or …

Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

Directing groups have been widely used in recent years to achieve control over all aspects
of reaction selectivity in a wide range of transformations involving transition‐metal catalysis …

The preparation of new enantiopure ligands that provide a chiral environment to metals so
that they perform efficient asymmetric catalysis is one of the most straightforward challenges …

Asymmetric catalysis is a challenge for chemists: How can we design catalysts to achieve
the goal of forming optically active compounds? This review provides the reader with an …

The development of methodologies for efficient asymmetric synthesis is one of the most
important areas of synthetic organic chemistry. 1 The syntheses of biologically relevant …

One of the potential benefits of allylic alkylations catalyzed by transition metals compared to
noncatalyzed processes is the prospect of excercising control of absolute stereochemistry by …

Phosphinooxazolines are highly effective ligands in Pd catalyzed asymmetric substitutions
of allylic compounds. Malonates, amines and nitronates can be employed successfully as …

Studies toward the development of an enantioselective diazomethane-based
cyclopropanation reagent derived from bis (oxazoline) palladium (II) complexes are …

Chiral bis (oxazoline)(BOX) ligands have been successfully used in the asymmetric catalysis
of a variety of reactions for the past decade. 1, 2 However, these versatile catalytic systems …