Within the realm of fluorinated reactive intermediates, the subject of fluorinated free radicals
is particularly rich and diverse. The primary goal within this review will be to provide the …

Herein, the development of visible light-mediated atom transfer radical addition (ATRA) of
haloalkanes onto alkenes and alkynes using the reductive and oxidative quenching of [Ir {dF …

All aspects of the structure, reactivity and chemistry of fluorine-containing, carbon-based free
radicals in solution are presented. The influence of fluorine substituents on the structure, the …

After a brief description of the various methods of telomer synthesis, the different types of
transfer agents and monomers are given, showing the extremely wide variety of …

Different methods of synthesis involved in the preparation of fluorinated telechelics (or α, ω-
difunctional compounds) from α, ω-diiodoperfluoroalkanes for obtaining well-defined …

An overview of the activities in fluorine chemistry at the Laboratory of Macromolecular
Chemistry of the Ecole Nationale Supérieure de Chimie de Montpellier is presented, ranging …

The radical addition of 1-iodoperfluorohexane (1) to allyl alcohol (2-propen-1-ol)(2) was
investigated in the presence of various initiating systems (photochemically or in the …

Data on fluoroalkylation and perfluoroalkylation methods in organic synthesis are analyzed,
summarized and described systematically. The most practically important properties of …

The approaches to the activation of perfluoroalkyl halides used as intermediates in the
synthesis of partially fluorinated compounds are considered. The conditions for reactions of …

A perfluorobutyl iodide-assisted transition-metal-free cyanomethylation of azoles and
phenols with acetonitrile in the presence of NaH has been developed. The reaction …