Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

The catalytic hydroboration of imines, nitriles, and carbodiimides is a powerful method of
preparing amines which are key synthetic intermediates in the synthesis of many value …

Abstract A series of mesoionic, 1, 2, 3‐triazole‐derived N‐heterocyclic olefins (mNHOs),
which have an extraordinarily electron‐rich exocyclic CC‐double bond, was synthesized …

The conjugated bis-guanidinate-supported zinc hydride [{LZnH} 2; L={(ArHN)(ArN)–C═ N–
C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](I)-catalyzed highly demanding exclusive 1, 2 …

This Perspective article highlights the recent development of mesoionic N-heterocyclic
olefins (mNHOs), where the exo-cyclic olefinic carbon is not bonded to strongly electron …

This review discusses the immense progress made over recent years in metal‐free catalytic
hydroboration. Reactions with several unsaturated functional groups, such as alkynes …

Regioselective hydroboration of pyridines to 1, 2-dihydropyridines remains a significant
challenge for the synthesis of valuable nitrogenous bioactive molecules. Herein, we report a …

Mesoionic polarization allows access to electron‐rich olefins that have found application as
organocatalysts, ligands, or nucleophiles. Herein, we report the synthesis and …

An efficient regioselective dearomatization of N-heteroarenes using a ruthenium precatalyst
[Ru-(p-cymene)(PCy3) Cl2] 1 is achieved. Reactions were performed under mild and neat …

N-heterocyclic olefins (NHOs) possess an electron-rich and highly polarized C= C double
bond due to the donating property of nitrogen atoms. This feature imparts exocyclic carbon …