Solvent effects in palladium catalysed cross-coupling reactions
J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …
Selectivity of C–H activation and competition between C–H and C–F bond activation at fluorocarbons
O Eisenstein, J Milani, RN Perutz - Chemical Reviews, 2017 - ACS Publications
Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …
Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions
In homogeneous catalysis, the main emphasis on improving catalyst performance (rate,
yield and selectivity) is directed towards manipulation of the ligands. The steric and …
yield and selectivity) is directed towards manipulation of the ligands. The steric and …
Luminescent cyclometalated-pentafluorophenyl PtII, PtIV and heteropolynuclear complexes
Platinum complexes bearing cyclometalating ligands possess impressive photophysical
properties that make these compounds desirable for optoelectronic and photonic …
properties that make these compounds desirable for optoelectronic and photonic …
AC^N Cycloplatinated(II) Fluoride Complex: Photophysical Studies and Csp3–F Bond Formation
This work reports the synthesis and characterization of a new C^ N-based cycloplatinated (II)
fluoride complex,[Pt (ppy)(PPh3) F](2; ppy= 2-phenylpyridinate), involving a Pt–F bond. The …
fluoride complex,[Pt (ppy)(PPh3) F](2; ppy= 2-phenylpyridinate), involving a Pt–F bond. The …
Facile Approaches to Phosphorescent Bis(cyclometalated) Pentafluorophenyl PtIV Complexes: Photophysics and Computational Studies
N Giménez, R Lara, MT Moreno… - Chemistry–A European …, 2017 - Wiley Online Library
A convenient and general strategy for the synthesis of stable bis (cyclometalated)
pentafluorophenyl PtIV complexes fac‐[Pt (C^ N) 2 (C6F5) Cl](3 a–f) and mer‐[Pt (C^ N) 2 …
pentafluorophenyl PtIV complexes fac‐[Pt (C^ N) 2 (C6F5) Cl](3 a–f) and mer‐[Pt (C^ N) 2 …
Selectivity in Competitive Csp2–Csp3 versus Csp3–Csp3 Reductive Eliminations at Pt(IV) Complexes: Experimental and Computational Approaches
F Niroomand Hosseini, SM Nabavizadeh… - …, 2021 - ACS Publications
Three classes of Pt (II) complexes of the types [PtMe2 (NHC)](NHC= 1, 1′-dimethyl-3, 3′-
methylenediimidazolin-2, 2′-diylidene),[PtMe2 (N^ N)](N^ N= 2, 2′-bipyridine, 1, 10 …
methylenediimidazolin-2, 2′-diylidene),[PtMe2 (N^ N)](N^ N= 2, 2′-bipyridine, 1, 10 …
Cross-Coupling versus Homo-Coupling at a Pt (IV) Center: Computational and Experimental Approaches
M Bavi, SM Nabavizadeh, FN Hosseini… - …, 2023 - ACS Publications
C–C cross-coupling versus homo-coupling from the Pt (IV) complex [Pt (pbt) Br (CH2Ph)(Me)
2], 2a (pbt= 2-(2-pyridyl) benzothiazole), was studied experimentally and through density …
2], 2a (pbt= 2-(2-pyridyl) benzothiazole), was studied experimentally and through density …
Photophysical and DFT studies on cycloplatinated complexes: modification in luminescence properties by expanding of π-conjugated systems
To investigate the factors influencing the luminescent properties of cycloplatinated
complexes containing aryl and SMe2 ligands, a detailed study of the photophysical and …
complexes containing aryl and SMe2 ligands, a detailed study of the photophysical and …
Carbon–Oxygen Bond Forming Reductive Elimination from Cycloplatinated (IV) Complexes
MD Aseman, SM Nabavizadeh… - …, 2018 - ACS Publications
The synthesis of the two cycloplatinated (IV) complexes [PtMe (OAc) 2 (C∧ N)(H2O)](C∧
N= 2-phenylpyridinate (2a), benzo [h] quinolate, 2b) by reaction of [PtMe (C∧ N)(SMe2)] …
N= 2-phenylpyridinate (2a), benzo [h] quinolate, 2b) by reaction of [PtMe (C∧ N)(SMe2)] …