Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

A review of grain boundary and heterointerface characterization in polycrystalline oxides by (scanning) transmission electron microscopy

H Vahidi, K Syed, H Guo, X Wang, JL Wardini… - Crystals, 2021 - mdpi.com
Interfaces such as grain boundaries (GBs) and heterointerfaces (HIs) are known to play a
crucial role in structure-property relationships of polycrystalline materials. While several …

Periodic segregation of solute atoms in fully coherent twin boundaries

JF Nie, YM Zhu, JZ Liu, XY Fang - Science, 2013 - science.org
The formability and mechanical properties of many engineering alloys are intimately related
to the formation and growth of twins. Understanding the structure and chemistry of twin …

Direct observation of individual dislocation interaction processes with grain boundaries

S Kondo, T Mitsuma, N Shibata, Y Ikuhara - Science advances, 2016 - science.org
In deformation processes, the presence of grain boundaries has a crucial influence on
dislocation behavior; these boundaries drastically change the mechanical properties of …

Unveiling of interstice-occupying dopant segregation at grain boundaries in perovskite oxide dielectrics for a new class of ceramic capacitors

JS An, HS Lee, P Byeon, D Kim, HB Bae… - Energy & …, 2023 - pubs.rsc.org
When aliovalent foreign cations are doped into ABO3-type perovskite oxides, they are
usually substituted for either dodecahedral A or octahedral B sites, depending on their …

Atomic-Scale Measurement of Flexoelectric Polarization at Dislocations

P Gao, S Yang, R Ishikawa, N Li, B Feng, A Kumamoto… - Physical review …, 2018 - APS
Owing to the broken translational symmetry at dislocations, a strain gradient naturally exists
around the dislocation cores and can significantly influence the electrical and mechanical …

Atomically ordered solute segregation behaviour in an oxide grain boundary

B Feng, T Yokoi, A Kumamoto, M Yoshiya… - Nature …, 2016 - nature.com
Grain boundary segregation is a critical issue in materials science because it determines the
properties of individual grain boundaries and thus governs the macroscopic properties of …

Large magnetoelectric coupling in magnetically short-range ordered Bi5Ti3FeO15 film

H Zhao, H Kimura, Z Cheng, M Osada, J Wang… - Scientific reports, 2014 - nature.com
Multiferroic materials, which offer the possibility of manipulating the magnetic state by an
electric field or vice versa, are of great current interest. However, single-phase materials with …

A reproducible method for damage‐free site‐specific preparation of atom probe tips from interfaces

PJ Felfer, T Alam, SP Ringer… - … research and technique, 2012 - Wiley Online Library
Atom probe tomography (APT) is a mass spectrometry method with atomic‐scale spatial
resolution that can be used for the investigation of a wide range of materials. The main …

Grain boundary structural transformation induced by co-segregation of aliovalent dopants

T Futazuka, R Ishikawa, N Shibata, Y Ikuhara - Nature Communications, 2022 - nature.com
Impurity doping is a conventional but one of the most effective ways to control the functional
properties of materials. In insulating materials, the dopant solubility limit is considerably low …