Photochemistry and astrochemistry: Photochemical pathways to interstellar complex organic molecules

KI Öberg - Chemical reviews, 2016 - ACS Publications
The interstellar medium is characterized by a rich and diverse chemistry. Many of its
complex organic molecules are proposed to form through radical chemistry in icy grain …

Grain surface models and data for astrochemistry

HM Cuppen, C Walsh, T Lamberts, D Semenov… - Space Science …, 2017 - Springer
The cross-disciplinary field of astrochemistry exists to understand the formation, destruction,
and survival of molecules in astrophysical environments. Molecules in space are …

Photodesorption of ices I: CO, and

KI Öberg, EF van Dishoeck, H Linnartz - Astronomy & Astrophysics, 2009 - aanda.org
Context. A longstanding problem in astrochemistry is how molecules can be maintained in
the gas phase in dense inter-and circumstellar regions at temperatures well below their …

Vacuum-UV spectroscopy of interstellar ice analogs-I. Absorption cross-sections of polar-ice molecules

GA Cruz-Diaz, GMM Caro, YJ Chen, TS Yih - Astronomy & Astrophysics, 2014 - aanda.org
Context. The vacuum-UV (VUV) absorption cross sections of most molecular solids present
in interstellar ice mantles with the exception of H 2 O, NH 3, and CO 2 have not been …

Photodesorption of water ice-A molecular dynamics study

S Andersson, EF Van Dishoeck - Astronomy & Astrophysics, 2008 - aanda.org
Context. Absorption of ultraviolet radiation by water ice coating interstellar grains can lead to
dissociation and desorption of the ice molecules. These processes are thought to be …

Photodesorption of CO ice

KI Öberg, GW Fuchs, Z Awad, HJ Fraser… - The Astrophysical …, 2007 - iopscience.iop.org
At the high densities and low temperatures found in star-forming regions, all molecules other
than H 2 should stick on dust grains on timescales shorter than the cloud lifetimes. Yet these …

Formation of complex organic molecules in methanol and methanol–carbon monoxide ices exposed to ionizing radiation–a combined FTIR and reflectron time-of-flight …

S Maity, RI Kaiser, BM Jones - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
The radiation induced chemical processing of methanol and methanol–carbon monoxide
ices at 5.5 K exposed to ionizing radiation in the form of energetic electrons and subsequent …

Reprocessing of ices in turbulent protoplanetary disks: carbon and nitrogen chemistry

K Furuya, Y Aikawa - The Astrophysical Journal, 2014 - iopscience.iop.org
We study the influence of the turbulent transport on ice chemistry in protoplanetary disks,
focusing on carbon-and nitrogen-bearing molecules. Chemical rate equations are solved …

Vacuum ultraviolet emission spectrum measurement of a microwave-discharge hydrogen-flow lamp in several configurations: application to photodesorption of CO ice

YJ Chen, KJ Chuang, GMM Caro… - The Astrophysical …, 2013 - iopscience.iop.org
We report measurements of the vacuum ultraviolet (VUV) emission spectra of a microwave-
discharge hydrogen-flow lamp (MDHL), a common tool in astrochemistry laboratories …

Sulfur depletion in dense clouds and circumstellar regions-I. H2S ice abundance and UV-photochemical reactions in the H2O-matrix

A Jiménez-Escobar, GMM Caro - Astronomy & Astrophysics, 2011 - aanda.org
Aims. This work aims to study the unexplained sulfur depletion observed toward dense
clouds and protostars. Methods. We made simulation experiments of the UV …