Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions

A Iliescu, JJ Oppenheim, C Sun, M Dincǎ - Chemical Reviews, 2023 - ACS Publications
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Bridging the Gap between Industrial and Well‐Defined Supported Catalysts

C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …

Applications of light olefin oligomerization to the production of fuels and chemicals

CP Nicholas - Applied Catalysis A: General, 2017 - Elsevier
The oligomerization of the light olefins ethene, propene, and butenes into fuels and
chemicals has been investigated and commercially practiced for many years. While the area …

The role of acid and metal sites in hydrodeoxygenation of guaiacol over Ni/Beta catalysts

P Yan, MMJ Li, E Kennedy, A Adesina… - Catalysis Science & …, 2020 - pubs.rsc.org
Hydrodeoxygenation (HDO) of guaiacol over Ni metal supported on zeolites (H-Beta and H-
ZSM-5) with different Si/Al ratios (12.5, 25, 175) and different metal loadings (2.3–23.4 wt%) …

Coke formation during high-temperature CO2 electrolysis over AFeO3 (A= La/Sr) cathode: effect of A-site metal segregation

DJ Deka, J Kim, S Gunduz, D Jain, Y Shi… - Applied Catalysis B …, 2021 - Elsevier
In this study, strontium-doped lanthanum ferrite perovskite oxides (LSF) with different A-site
occupancies were used as cathode catalysts for CO 2 electrolysis at 800° C. XRD, EXAFS …

Structure and site evolution of framework Ni species in MIL-127 MOFs for propylene oligomerization catalysis

B Yeh, S Chheda, SD Prinslow… - Journal of the …, 2023 - ACS Publications
A mixed-valence oxotrimer metal–organic framework (MOF), Ni-MIL-127, with a fully
coordinated nickel atom and two iron atoms in the inorganic node, generates a missing …

Influence of 1-butene adsorption on the dimerization activity of single metal cations on UiO-66 nodes

L Löbbert, S Chheda, J Zheng… - Journal of the …, 2023 - ACS Publications
Grafting metal cations to missing linker defect sites in zirconium-based metal–organic
frameworks, such as UiO-66, produces a uniquely well-defined and homotopic catalytically …

[HTML][HTML] Highly productive framework bounded Ni2+ on hierarchical zeolite for ethylene oligomerization

HO Mohamed, VK Velisoju, I Hita, O Abed… - Chemical Engineering …, 2023 - Elsevier
The production of higher linear olefins via ethylene oligomerization is an applied industrial
process using homogeneous catalysts in the liquid phase. Heterogeneous catalysts based …

Highly-dispersed Ni on BEA catalyst prepared by ion-exchange-deposition-precipitation for improved hydrodeoxygenation activity

P Yan, J Mensah, A Adesina, E Kennedy… - Applied Catalysis B …, 2020 - Elsevier
BEA zeolite-supported nickel is a promising catalyst for the hydrodeoxygenation reaction. In
this study, highly dispersed Ni/BEA catalysts prepared via ion-exchange-deposition …

Ethene oligomerization in Ni-containing zeolites: theoretical discrimination of reaction mechanisms

RY Brogaard, U Olsbye - Acs Catalysis, 2016 - ACS Publications
Ni-containing porous aluminosilicates are promising heterogeneous catalysts for
oligomerization of ethene, but little is known about the catalytic cycle. In addition, it remains …