Asymmetric heterogeneous catalysis: science and engineering

DY Murzin, P Mäki‐Arvela, E Toukoniitty… - Catalysis Reviews, 2005 - Taylor & Francis
Asymmetric heterogeneous catalysis is a vivid branch of catalysis, remaining, however,
largely a domain of organic chemists. The view towards asymmetric heterogeneous …

Catalytic hydrogenation/hydrogenolysis of 5‐hydroxymethylfurfural to 2, 5‐dimethylfuran

P Mäki‐Arvela, D Ruiz, DY Murzin - ChemSusChem, 2021 - Wiley Online Library
Recent developments in transformations of biobased 5‐hydroxymethylfurfural to 2, 5‐
dimethylfuran, a potential liquid fuel, are critically summarized. The highest yield of 2, 5 …

Particle size effect in liquid-phase hydrogenation of phenylacetylene over Pd catalysts: Experimental data and theoretical analysis

PV Markov, IS Mashkovsky, GO Bragina… - Chemical Engineering …, 2019 - Elsevier
The liquid-phase hydrogenation of phenylacetylene (PA) over 1 wt% Pd/Al 2 O 3 catalysts
with the mean palladium cluster size varying from 1.5 to 22 nm was studied at 5 bar H 2 …

Kinetic Modeling of Erythritol Deoxydehydration and Consecutive Hydrogenation over the ReOx-Pd/CeO2 Catalyst

J Cao, S Larasati, M Yabushita, Y Nakagawa… - ACS …, 2024 - ACS Publications
The reaction kinetics of deoxydehydration+ hydrogenation (DODH+ HG; didehydroxylation)
of erythritol to butanediols and n-butane over the ReO x-Pd/CeO2 catalyst was investigated …

Mild oxalic‐acid‐catalyzed hydrolysis as a novel approach to prepare cellulose nanocrystals

W Xu, H Grénman, J Liu, D Kronlund, B Li… - …, 2017 - Wiley Online Library
The traditional method to isolate cellulose nanocrystals (CNCs) is to subject cellulosic
materials to strong acid hydrolysis by mineral acids, which usually causes problems such as …

Citral-to-menthol transformations in a continuous reactor over Ni/mesoporous aluminosilicate extrudates containing a sepiolite clay binder

IL Simakova, Z Vajglová, P Maki-Arvela… - … Process Research & …, 2022 - ACS Publications
One-pot continuous synthesis of menthols from citral was performed over 5 wt% Ni
supported on a mesoporous aluminosilicate catalyst with sepiolite as a binder at 70° C with …

Oxidative dehydrogenation of ethanol on gold: Combination of kinetic experiments and computation approach to unravel the reaction mechanism

E Behravesh, MM Melander, J Wärnå, T Salmi… - Journal of …, 2021 - Elsevier
Selective alcohol dehydrogenation on heterogeneous catalysts is a key industrial reaction
for production of aldehydes, ketones, and carboxylic compounds. Design of catalysts with …

Sugar hydrogenation over a Ru/C catalyst

VA Sifontes Herrera, O Oladele… - Journal of Chemical …, 2011 - Wiley Online Library
BACKGROUND: In recent years, exploitation of renewable resources has gained
considerable attention. In this respect, polyols derived from the hydrogenation of sugar …

Acetyl group migration across the saccharide units in oligomannoside model compound

R Lassfolk, J Rahkila, MP Johansson… - Journal of the …, 2018 - ACS Publications
Acetylated oligosaccharides are common in nature. While they are involved in several
biochemical and biological processes, the role of the acetyl groups and the complexity of …

Kinetics of aqueous extraction of hemicelluloses from spruce in an intensified reactor system

H Grénman, K Eränen, J Krogell… - Industrial & …, 2011 - ACS Publications
The aqueous extraction of hemicelluloses has gained increasing interest with new emerging
applications for hemicelluloses in the modern forest-based biorefinery concept. The …