Diastereoselective Homocoupling of Benzylic C(sp3)–H Bonds Enabled by Halogen Transfer
X Liu, X An, X Zhao, S Luo, L Xu, M Zhan - Organic Letters, 2024 - ACS Publications
A transition-metal-and harsh-oxidant-free strategy for diastereoselective homocoupling of
benzylic α-boryl carbanions has been developed. Central to this methodology is the ability of …
benzylic α-boryl carbanions has been developed. Central to this methodology is the ability of …
Neglected no longer: Selective C–H activation of the non-resonant C3 benzylic position of pyridine
K Le, JF Van Humbeck - Chem, 2024 - cell.com
Unlike the 2-and 4-positions, benzylic C (sp 3)–H sites in 3-alkylpyridines have no direct
communication with the pyridine nitrogen and are not susceptible to traditional forms of …
communication with the pyridine nitrogen and are not susceptible to traditional forms of …
[图书][B] Expanding Benzylic C–H Diversification via C–H Chlorination/Functionalization Strategies
MA Lopez - 2023 - search.proquest.com
Alkyl chlorides can be employed in a range of C–C, C–O, C–N, and C–S bond forming
reactions, making them valuable precursors in the synthesis of diverse drug-like compounds …
reactions, making them valuable precursors in the synthesis of diverse drug-like compounds …