Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure

RH Crabtree - Chemical reviews, 2015 - ACS Publications
Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

Recent advances in pincer–nickel catalyzed reactions

V Arora, H Narjinari, PG Nandi, A Kumar - Dalton Transactions, 2021 - pubs.rsc.org
Organometallic catalysts have played a key role in accomplishing numerous synthetically
valuable organic transformations that are either otherwise not possible or inefficient. The use …

[图书][B] Pincer and pincer-type complexes: applications in organic synthesis and catalysis

KJ Szabó, OF Wendt - 2014 - books.google.com
This new book on this hot topic summarizes the key achievements for the synthesis and
catalytic applications of pincer and pincer-type complexes, providing readers with the latest …

Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials

T Chantarojsiri, JW Ziller, JY Yang - Chemical science, 2018 - pubs.rsc.org
The synthesis and characterization of the Schiff base complexes Fe (II)(2M) and Fe (III) Cl
(3M), where M is a K+ or Ba2+ ion incorporated into the ligand, are reported. The Fe (III/II) …

Hydration of nitriles using a metal–ligand cooperative ruthenium pincer catalyst

B Guo, JG de Vries, E Otten - Chemical Science, 2019 - pubs.rsc.org
Nitrile hydration provides access to amides that are important structural elements in organic
chemistry. Here we report catalytic nitrile hydration using ruthenium catalysts based on a …

Metal-catalyzed nitrile hydration reactions: The specific contribution of ruthenium

R García-Álvarez, J Francos, E Tomás-Mendivil… - Journal of …, 2014 - Elsevier
The hydration of nitriles is an atom economical route to generate primary amides of great
academic and industrial significance. From an academic perspective, considerable progress …

Hydration of Nitriles Catalyzed by Ruthenium Complexes: Role of Dihydrogen Bonding Interactions in Promoting Base-Free Catalysis

S Yadav, R Gupta - Inorganic Chemistry, 2022 - ACS Publications
Ru (II) complexes of amide-phosphine-based tridentate ligands additionally containing
pyridine, isoquinoline, and quinoline rings have been synthesized, and their catalytic utility …

An efficient ruthenium (IV) catalyst for the selective hydration of nitriles to amides in water under mild conditions

E Tomás-Mendivil, FJ Suarez, J Diez… - Chemical …, 2014 - pubs.rsc.org
An efficient ruthenium( iv ) catalyst for the selective hydration of nitriles to amides in water under
mild conditions - Chemical Communications (RSC Publishing) DOI:10.1039/C4CC04058A …

Thiazolyl-phosphine hydrochloride salts: effective auxiliary ligands for ruthenium-catalyzed nitrile hydration reactions and related amide bond forming processes in …

R García-Álvarez, M Zablocka, P Crochet… - Green chemistry, 2013 - pubs.rsc.org
A series of water-soluble N-protonated thiazolyl-phosphine hydrochloride salts have been
synthesized and coordinated to the ruthenium (II) fragment [RuCl2 (η6-p-cymene)]. The …

Nanoparticle catalysts for nitrile hydration

EL Downs, DR Tyler - Coordination Chemistry Reviews, 2014 - Elsevier
The transition metal-catalyzed hydration of nitriles is an efficient route to amides, which are
important synthetic building blocks. Many heterogeneous and homogeneous catalysts have …