Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers

I Luzinov, S Minko, VV Tsukruk - Progress in Polymer Science, 2004 - Elsevier
The present manuscript offers an overview of the current state of affairs within the research
field of adaptive and environmentally sensitive polymer surfaces designed to respond to …

Polymer brushes on flat and curved surfaces: How computer simulations can help to test theories and to interpret experiments

K Binder, A Milchev - Journal of Polymer Science Part B …, 2012 - Wiley Online Library
Theoretical descriptions of static properties of polymer brushes are reviewed, with an
emphasis on monodisperse macromolecules grafted to planar, cylindrical, or spherical …

50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials

WL Chen, R Cordero, H Tran, CK Ober - Macromolecules, 2017 - ACS Publications
Polymer brushes have become a significant focus of polymer research with the need for
straightforward and versatile surface modification. With the development of controlled radical …

Multivalent counterions diminish the lubricity of polyelectrolyte brushes

J Yu, NE Jackson, X Xu, Y Morgenstern, Y Kaufman… - Science, 2018 - science.org
Polyelectrolyte brushes provide wear protection and lubrication in many technical, medical,
physiological, and biological applications. Wear resistance and low friction are attributed to …

Synthesis of adaptive polymer brushes via “grafting to” approach from melt

S Minko, S Patil, V Datsyuk, F Simon, KJ Eichhorn… - Langmuir, 2002 - ACS Publications
We report a simple method to synthesize binary polymer brushes from two incompatible
polymers of different polarity. The synthetic route is based on a subsequent step-by-step …

Controlled switchable surface

Y Liu, L Mu, B Liu, J Kong - Chemistry–A European Journal, 2005 - Wiley Online Library
The macroscopic properties of a surface can be intelligently controlled by alternating the
states of the modified molecules, such as polymers, metallic oxide, or self‐assembled …

Reorganization of binary polymer brushes: Reversible switching of surface microstructures and nanomechanical properties

M Lemieux, D Usov, S Minko, M Stamm… - …, 2003 - ACS Publications
For a binary polymer brush layer, we investigated the morphological state, the structure
reordering, and the nanomechanical properties as a function of treatment with selective …

Multivalent ions induce lateral structural inhomogeneities in polyelectrolyte brushes

J Yu, NE Jackson, X Xu, BK Brettmann, M Ruths… - Science …, 2017 - science.org
Subtle details about a polyelectrolyte's surrounding environment can dictate its structural
features and potential applications. Atomic force microscopy (AFM), surface forces …

Surface forces and nanorheology of molecularly thin films

M Ruths, JN Israelachvili - Nanotribology and Nanomechanics II …, 2011 - Springer
In this chapter, we describe the static and dynamic normal forces that occur between
surfaces in vacuum or liquids and the different modes of friction that can be observed …

Y-shaped polymer brushes: Nanoscale switchable surfaces

D Julthongpiput, YH Lin, J Teng, ER Zubarev… - Langmuir, 2003 - ACS Publications
We report a first observation of nanoscale surface structures of segregated pinned micelles
of grafted Y-shaped molecules and their reversible structural reorganization. We designed a …