Crystallization in thin films of polymer glasses: The role of free surfaces, solid interfaces and their competition

Y Yang, H Tian, S Napolitano, B Zuo - Progress in Polymer Science, 2023 - Elsevier
Polymer coatings of nanometric thickness are about to enter in everyday life as part of a
wide range of applications such as protective layers, stimuli-responsive membranes or as …

6 Studies of spin-coated polymer films

K Norrman, A Ghanbari-Siahkali… - Annual Reports Section" C …, 2005 - pubs.rsc.org
Spin-coating is widely employed for the highly reproducible fabrication of thin film coatings
over large areas with high structural uniformity. Research in recent years has extended the …

Functionalized graphene sheets for polymer nanocomposites

T Ramanathan, AA Abdala, S Stankovich… - Nature …, 2008 - nature.com
Polymer-based composites were heralded in the 1960s as a new paradigm for materials. By
dispersing strong, highly stiff fibres in a polymer matrix, high-performance lightweight …

Polymer nanocomposites: a small part of the story

LS Schadler, LC Brinson, WG Sawyer - Jom, 2007 - Springer
Polymer nanocomposites are polymer matrix composites in which the fillers are less than
100 nm in at least one dimension. These composites have exhibited extraordinarily …

A review on the progress of polymer nanostructures with modulated morphologies and properties, using nanoporous AAO templates

C Mijangos, R Hernández, J Martin - Progress in Polymer Science, 2016 - Elsevier
Polymers with the same chemical composition can provide different properties by reducing
the dimension or simply by altering their nanostructure. The recent literature reports …

Shear modulation force microscopy study of near surface glass transition temperatures

S Ge, Y Pu, W Zhang, M Rafailovich, J Sokolov… - Physical Review Letters, 2000 - APS
We report results of glass transition (T g) measurements for polymer thin films using atomic
force microscopy (AFM). The AFM mode, shear modulation force microscopy (SMFM) …

Molecular dynamics simulation of a polymer melt/solid interface: Local dynamics and chain mobility in a thin film of polyethylene melt adsorbed on graphite

VA Harmandaris, KC Daoulas, VG Mavrantzas - Macromolecules, 2005 - ACS Publications
Molecular dynamics (MD) simulations have been performed on a dense polymer melt
adsorbed on a solid substrate on the one side and exposed to vacuum on the other. As a …

Reduced polymer mobility near the polymer/solid interface as measured by neutron reflectivity

EK Lin, R Kolb, SK Satija, W Wu - Macromolecules, 1999 - ACS Publications
Neutron reflectometry is used to measure polymer mobility over distances less than 200 Å as
a function of distance from an attractive solid surface and molecular size. Effective diffusion …

Crystallization in the thin and ultrathin films of poly (ethylene− vinyl acetate) and linear low-density polyethylene

Y Wang, S Ge, M Rafailovich, J Sokolov, Y Zou… - …, 2004 - ACS Publications
The crystallization of poly (ethylene− vinyl acetate) and linear low-density polyethylene
(LLDPE) films spun-cast from the polymer/toluene solutions with as-cast thickness from 460 …

Extraordinary elevation of the glass transition temperature of thin polymer films grafted to silicon oxide substrates

RS Tate, DS Fryer, S Pasqualini… - The Journal of …, 2001 - pubs.aip.org
We used local thermal analysis and ellipsometry to measure the glass transition
temperatures (T g) of supported thin films of poly (4-hydroxystyrene)(PHS) and hydroxy …