Photo-and thermal-oxidation of polyethylene: Comparison of mechanisms and influence of unsaturation content

M Gardette, A Perthue, JL Gardette, T Janecska… - Polymer Degradation …, 2013 - Elsevier
The behaviour of polyethylene with different contents in vinyl and t-vinylene groups have
been studied by photooxidation with λ≥ 300 nm light or by thermooxidation at a temperature …

Cryogenic properties of polymers

O Yano, H Yamaoka - Progress in Polymer Science, 1995 - Elsevier
The cryogenic properties of polymers are recently drawing attention with new developments
in space, superconducting magnet and electronic technologies. Requirements for polymeric …

[HTML][HTML] Micro (nano) plastics from synthetic oligomers persisting in Mediterranean seawater: Comprehensive NMR analysis, concerns and origins

A Giannattasio, V Iuliano, G Oliva, D Giaquinto… - Environment …, 2024 - Elsevier
The presence in seawater of low-molecular-weight polyethylene (PE) and
polydimethylsiloxane (PDMS), synthetic polymers with high chemical resistance, has been …

A quantitative analysis of low-density (branched) polyethylenes by carbon-13 Fourier transform nuclear magnetic resonance at 67.9 MHz

DE Axelson, GC Levy, L Mandelkern - Macromolecules, 1979 - ACS Publications
By utilizing predetermined equilibrium magnetization conditionsand the measured nuclear
Overhauser enhancement factors for the appropriate carbon atoms, we have obtained …

Mild Catalytic Degradation of Crystalline Polyethylene Units in a Solid State Assisted by Carboxylic Acid Groups

B Lu, K Takahashi, J Zhou, S Nakagawa… - Journal of the …, 2024 - ACS Publications
Crystalline polyethylenes bearing carboxylic acid groups in the main chain were
successfully degraded with a Ce catalyst and visible light. The reaction proceeds in a …

Polyolefin oxidation: quantification of alcohol and hydroperoxide products by nitric oxide reactions

DJ Carlsson, R Brousseau, C Zhang… - Polymer degradation and …, 1987 - Elsevier
A new procedure has been developed for the identification and quantification of key
products from the oxidation of solid polyolefins, based on reactions with gaseous nitric …

Identification of products from polyolefin oxidation by derivatization reactions

DJ Carlsson, R Brousseau, C Zhang, DM Wiles - 1988 - ACS Publications
A series of reactions with gases have been selected for the rapid quantification of many of
the major products from the oxidation of polyolefins. Infrared spectroscopy is used to …

A review of the methods for detecting and characterizing hydroperoxide groups in oxidized polyolefins

J Scheirs, DJ Carlsson, SW Bigger - Polymer-Plastics Technology …, 1995 - Taylor & Francis
Hydroperoxide groups are widely believed to be critical intermediates in the oxidative
degradation of many polymers, especially commodity polyolefins [34, 5 1-53]. Trace …

Experimental and theoretical investigation of stress corrosion crack (SCC) growth of polyethylene pipes

BH Choi, A Chudnovsky, R Paradkar, W Michie… - … degradation and stability, 2009 - Elsevier
Degradation of polymers is usually manifested in a reduction of molecular weight, increase
of crystallinity in semicrystalline polymers, increase of material density, a subtle increase in …

Thermal degradation of crosslinked high density polyethylene

SO Han, DW Lee, OH Han - Polymer degradation and stability, 1999 - Elsevier
Thermal degradation of crosslinked high density polyethylene (HDPE) has been
investigated by the thermal and spectroscopic methods for development of HDPE as a …