In Situ and Operando X-ray Scattering Methods in Electrochemistry and Electrocatalysis

OM Magnussen, J Drnec, C Qiu, I Martens… - Chemical …, 2024 - ACS Publications
Electrochemical and electrocatalytic processes are of key importance for the transition to a
sustainable energy supply as well as for a wide variety of other technologically relevant …

Long range interactions in nanoscale science

RH French, VA Parsegian, R Podgornik, RF Rajter… - Reviews of Modern …, 2010 - APS
Our understanding of the “long range” electrodynamic, electrostatic, and polar interactions
that dominate the organization of small objects at separations beyond an interatomic bond …

Monovalent ion adsorption at the muscovite (001)–solution interface: Relationships among ion coverage and speciation, interfacial water structure, and substrate …

SS Lee, P Fenter, KL Nagy, NC Sturchio - Langmuir, 2012 - ACS Publications
The interfacial structure between the muscovite (001) surface and aqueous solutions
containing monovalent cations (3× 10–3 m Li+, Na+, H3O+, K+, Rb+, or Cs+, or 3× 10–2 m …

Hydrated cation speciation at the muscovite (001)− water interface

SS Lee, P Fenter, C Park, NC Sturchio, KL Nagy - Langmuir, 2010 - ACS Publications
Charged materials in aqueous systems interact according to their interfacial properties,
typically described by the electrical double layer (EDL). Distributions of divalent metal …

Bioavailability of barium to plants and invertebrates in soils contaminated by barite

DT Lamb, VP Matanitobua, T Palanisami… - … science & technology, 2013 - ACS Publications
Barium (Ba) is a nonessential element to terrestrial organisms and is known to be toxic at
elevated concentrations. In this study, the bioavailability and toxicity of Ba in barite (BaSO4) …

Analytical approaches to the speciation of lanthanides at solid-water interfaces

X Tan, X Ren, C Chen, X Wang - TrAC Trends in Analytical Chemistry, 2014 - Elsevier
We review the analysis of lanthanide speciation at solid-water interfaces. We summarize the
various mechanisms of lanthanide interaction with sorbent surfaces, such as surface …

Ion distribution and hydration structure in the stern layer on muscovite surface

K Kobayashi, Y Liang, S Murata, T Matsuoka… - Langmuir, 2017 - ACS Publications
Based on molecular dynamics simulations of eight ions (Na+, K+, Rb+, Cs+, Mg2+, Ca2+,
Sr2+, and Ba2+) on muscovite mica surfaces in water, we demonstrate that experimental …

Direct Experimental Observations of Ion Distributions during Overcharging at the Muscovite‐Water Interface by Adsorption of Rb+ and Halides (Cl, Br, I) at High …

J Neumann, SS Lee, EJ Zhao, P Fenter - ChemPhysChem, 2023 - Wiley Online Library
Classical electric double layer (EDL) models have been widely used to describe ion
distributions at charged solid‐water interfaces in dilute electrolytes. However, the chemistry …

A mechanistic exploration of natural organic matter aggregation and surface complexation in smectite mesopores

N Loganathan, BO Ferguson, B Arey… - The Journal of …, 2020 - ACS Publications
Soil minerals and organic matter play critical roles in nutrient cycling and other life-essential
biogeochemical processes, yet the structural and dynamical details of natural organic matter …

Hydration structure of the barite (001)–water interface: Comparison of x-ray reflectivity with molecular dynamics simulations

JN Bracco, SS Lee, JE Stubbs, PJ Eng… - The Journal of …, 2017 - ACS Publications
The three-dimensional structure of the barite (001)–water interface was studied using in situ
specular and nonspecular X-ray reflectivity (XR). Displacements of the barium and sulfate …