[HTML][HTML] Multinuclear metal catalysts in ring-opening polymerization of ε‑caprolactone and lactide: Cooperative and electronic effects between metal centers

LJ Wu, W Lee, PK Ganta, YL Chang, YC Chang… - Coordination Chemistry …, 2023 - Elsevier
Multinuclear metal complexes can effectively improve the catalytic activity of catalysts for ring-
opening polymerization (ROP) of cyclic esters. If the catalytic metal centers are close enough …

Exploiting multimetallic cooperativity in the ring-opening polymerization of cyclic esters and ethers

U Yolsal, PJ Shaw, PA Lowy, R Chambenahalli… - ACS …, 2024 - ACS Publications
The use of multimetallic complexes is a rapidly advancing route to enhance catalyst
performance in the ring-opening polymerization of cyclic esters and ethers. Multimetallic …

Studies on two phenoxo-bridged homopolynuclear Cu (II) bis (salamo) type complexes based on theoretical calculations and fluorescence properties

J Zhang, LC Feng, SZ Li, WK Dong - Polyhedron, 2022 - Elsevier
The dinuclear Cu (II) complex [Cu 2 (HL) Br 2 (MeOH)]· MeOH (1) and the tetranuclear Cu (II)
complex [Cu 4 (L) 2](ClO 4) 2· 2EtOH (2), based on a new bis (salamo) type ligand H 3 L …

Exploring two helical centrosymmetric homotetranuclear Cu (II) bis (salamo)‐based complexes

RY Li, L Dou, L Tong, WK Dong - Applied Organometallic …, 2022 - Wiley Online Library
Two helical centrosymmetric homotetranuclear Cu (II) complexes,[Cu4 (L) 2 (EtOH) 2](ClO4)
2· 2EtOH· 2CHCl3 (1) and [{Cu4 (L) 2 (EtOH) 2}{Cu4 (L) 2 (HNO3) 2}](NO3) 4· 3EtOH …

Stereoselective synthesis of biodegradable polymers by salen-type metal catalysts

X Liao, Y Su, X Tang - Science China Chemistry, 2022 - Springer
Biodegradable polymers are a promising sustainable alternative to conventional petroleum-
based polymers and have attracted recent extensive research interest due to their potential …

The investigation of two bis (phenoxo)-acetate-bridged binuclear nickel (II) complexes driven by different alcohol solvents

J Zhang, L Dou, ZF Hu, WK Dong - Journal of Coordination …, 2023 - Taylor & Francis
Two solvent-induced bis (phenoxo)-acetate-bridged binuclear Ni (II) complexes,[Ni2 (L)(µ-
OAc)(CH3OH)](1) and [Ni2 (L)(µ-OAc)(H2O)](2), were synthesized with a bis (salamo)-like …

Lewis acidic zinc (II) salen-type Schiff-base complexes: Sensing properties and responsive nanostructures

SD Bella - Dalton Transactions, 2021 - pubs.rsc.org
In this frontier article some peculiar characteristics of Zn (salen)-type Schiff-base complexes
are reviewed. The paper is mainly focused on the most recent and relevant achievements on …

Homoleptic phenoxy-imine pyridine zinc complexes: efficient catalysts for solvent free synthesis and chemical degradation of polyesters

S D'Aniello, S Laviéville, F Santulli, M Simon… - Catalysis Science & …, 2022 - pubs.rsc.org
The synthesis and structural characterization of six homoleptic zinc complexes supported by
monoanionic phenoxy-imine pyridine ligands bearing different substituents on the phenoxy …

Synthesis, characterization and discovery of multiple anticancer mechanisms of dibutyltin complexes based on salen-like ligands

W Tian, W Zhong, Z Yang, L Chen, S Lin, Y Li… - Journal of Inorganic …, 2024 - Elsevier
A series of novel dibutyltin complexes based on salen-like ligands (S01–S03) were
synthesized and characterized using ultraviolet-visible spectra, infrared spectra, 1 H, 13 C …

Zinc and magnesium catalysts for the synthesis for PLA and its degradation: Clues for catalyst design

F Santulli, G Gravina, M Lamberti, C Tedesco… - Molecular …, 2022 - Elsevier
Homoleptic and heteroleptic zinc and magnesium complexes bearing phenoxy-imine
pyridine ligands were synthetized and characterized. Several structural parameters such as …