Hydrides of the main-group metals: New variations on an old theme

S Aldridge, AJ Downs - Chemical reviews, 2001 - ACS Publications
For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Intramolecular london dispersion interaction effects on gas-phase and solid-state structures of diamondoid dimers

AA Fokin, TS Zhuk, S Blomeyer, C Perez… - Journal of the …, 2017 - ACS Publications
The covalent diamantyl (C28H38) and oxadiamantyl (C26H34O2) dimers are stabilized by
London dispersion attractions between the dimer moieties. Their solid-state and gas-phase …

New implementation of the first-order perturbation theory for calculation of interatomic vibrational amplitudes and corrections in gas electron diffraction

YV Vishnevskiy, YA Zhabanov - Journal of Physics: Conference …, 2015 - iopscience.iop.org
The problem of computation of vibrational molecular parameters in models of gas electron
diffraction is discussed. Some peculiarities of the standard for these purposes Shrink …

Recent advances in the chemistry of the Group 13 metals: hydride derivatives and compounds involving multiply bonded Group 13 metal atoms

AJ Downs - Coordination chemistry reviews, 1999 - Elsevier
Two aspects of Group 13 metal chemistry are surveyed in the light of recent research,
particularly that reported in the period 1992–1998. The first concerns compounds containing …

Spontaneous Generation of Stable Pnictinyl Radicals from “Jack-in-the-Box” Dipnictines: A Solid-State, Gas-Phase, and Theoretical Investigation of the Origins of …

SL Hinchley, CA Morrison, DWH Rankin… - Journal of the …, 2001 - ACS Publications
The molecular structures of the stable phosphinyl and arsinyl radicals,• PnR2 [Pn= P (2); As
(4); R= CH (SiMe3) 2], have been determined by gas-phase electron diffraction (GED) in …

SARACEN–molecular structures from theory and experiment: the best of both worlds

NW Mitzel, DWH Rankin - Dalton Transactions, 2003 - pubs.rsc.org
Structures of molecules in the gas phase, determined experimentally, provide definitive
information about their identity, reactivity and other properties, free from intermolecular …

Structures and Aggregation of the Methylamine−Borane Molecules, MenH3−nN·BH3 (n = 1−3), Studied by X-ray Diffraction, Gas-Phase Electron Diffraction, and …

S Aldridge, AJ Downs, CY Tang… - Journal of the …, 2009 - ACS Publications
The structures of the molecules methylamine− borane, MeH2N· BH3, and dimethylamine−
borane, Me2HN· BH3, have been investigated by gas-phase electron diffraction (GED) and …

Tetraborane (10), B 4 H 10: structures in gaseous and crystalline phases

PT Brain, CA Morrison, S Parsons… - Journal of the Chemical …, 1996 - pubs.rsc.org
Supplementing gas-phase electron-diffraction data with restraints derived from a graded
series of ab initio calculations makes possible refinement of all geometrical parameters and …

The molecular structure of tetra-tert-butyldiphosphine: an extremely distorted, sterically crowded molecule

SL Hinchley, HE Robertson, KB Borisenko… - Dalton …, 2004 - pubs.rsc.org
The molecular structure of tetra-tert-butyldiphosphine has been determined in the gas phase
by electron diffraction using the new DYNAMITE method and in the crystalline phase by X …

Three-Membered Ring or Open Chain Molecule − (F3C)F2SiONMe2 a Model for the α-Effect in Silicon Chemistry

NW Mitzel, K Vojinović, R Fröhlich… - Journal of the …, 2005 - ACS Publications
(F3C) F2SiONMe2 was prepared from LiONMe2 and F3CSiF3. It was characterized by gas
IR and multinuclear solution NMR spectroscopy and by mass spectrometry. Its structure was …