Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Targeted modifications in ionic liquids–from understanding to design

F Philippi, T Welton - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Ionic liquids are extremely versatile and continue to find new applications in academia as
well as industry. This versatility is rooted in the manifold of possible ion types, ion …

Flexibility is the key to tuning the transport properties of fluorinated imide-based ionic liquids

F Philippi, D Rauber, O Palumbo, K Goloviznina… - Chemical …, 2022 - pubs.rsc.org
Ionic liquids are becoming increasingly popular for practical applications such as biomass
processing and lithium-ion batteries. However, identifying ionic liquids with optimal …

Nanosegregation and Structuring in the Bulk and at the Surface of Ionic-Liquid Mixtures

DW Bruce, CP Cabry, JN Canongia Lopes… - The Journal of …, 2017 - ACS Publications
Ionic-liquid (IL) mixtures hold great promise, as they allow liquids with a wide range of
properties to be formed by mixing two common components rather than by synthesizing a …

Structural and aggregate analyses of (Li salt+ glyme) mixtures: the complex nature of solvate ionic liquids

K Shimizu, AA Freitas, R Atkin, GG Warr… - Physical Chemistry …, 2015 - pubs.rsc.org
The structure and interactions of different (Li salt+ glyme) mixtures, namely equimolar
mixtures of lithium bis (trifluoromethylsulfonyl) imide, nitrate or trifluoroacetate salts …

Temperature Dependence of Short and Intermediate Range Order in Molten MgCl2 and Its Mixture with KCl

F Wu, S Sharma, S Roy, P Halstenberg… - The Journal of …, 2020 - ACS Publications
This article addresses the non-Debye–Waller temperature behavior in the intermediate
range order for molten MgCl2 and its mixtures with KCl from a theory, Molecular Dynamics …

Self-diffusion, velocity cross-correlation, distinct diffusion and resistance coefficients of the ionic liquid [BMIM][Tf 2 N] at high pressure

KR Harris, M Kanakubo - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
Ion self-diffusion coefficients (DSi) have been measured for the ionic liquid 1-butyl-3-
methylimidazolium bis (trifluoromethanesulfonyl) amide [BMIM][Tf2N] at pressures to 200 …

Understanding the liquid structure in mixtures of ionic liquids with semiperfluoroalkyl or alkyl chains

NS Elstone, K Shimizu, EV Shaw… - The Journal of …, 2023 - ACS Publications
By mixing ionic liquids (ILs), it is possible to fine-tune their bulk and interfacial structure. This
alters their physical properties and solvation behavior and is a simple way to prepare a …

A thermophysical and structural characterization of ionic liquids with alkyl and perfluoroalkyl side chains

NSM Vieira, PM Reis, K Shimizu, OA Cortes… - Rsc Advances, 2015 - pubs.rsc.org
This work represents an essential step towards the understanding of the dynamics and
thermodynamic characteristics of a novel family of ionic liquids, namely fluorinated ionic …