Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Stereochemically defined tetrasubstituted olefins are widespread structural elements of
organic molecules and key intermediates in organic synthesis. However, flexible methods …

The cycloisomerization of enynes catalyzed by Pd (OAc) 2 and bis-benzylidene
ethylenediamine (bbeda) is a landmark methodology in transition-metal-catalyzed …

A palladium (II) complex [(κ4-{1, 2-C6H4 (NCH–C6H4O) 2} Pd](1) supported by a dianionic
salen ligand [1, 2-C6H4 (NCH–C6H4O) 2] 2−(L) was synthesised and used as a molecular …

Developing protocols for stereodivergent synthesis of multi-substituted alkenylboronates will
simplify and unify the synthesis of Z-and E-stereoisomers of multi-substituted alkenes …

An efficient pincer‐ligand‐based cobalt‐complex‐catalyzed allene hydroboration affording Z‐
allylic boronates is described. The reaction demonstrates an excellent regio‐as well as Z …

Organo-f-complexes catalyzing small molecule transformations have been a hot topic in the
past few years. Compared to other transformations, the hydroboration of C= X (X= C, N, O) …

A highly efficient palladium‐catalyzed oxidative borylation of enallenes was developed for
the selective formation of cyclobutene derivatives and fully‐substituted alkenylboron …

A palladium (II)-catalyzed hydroboration of aryl alkenes with stable and easy-to-handle
(pinacolato) diboron (B2pin2) under mild conditions has been developed. Acetic acid acted …