Long-range proton–carbon coupling constants: NMR methods and applications

T Parella, JF Espinosa - Progress in Nuclear Magnetic Resonance …, 2013 - Elsevier
A general review of novel NMR methods to measure heteronuclear long-range proton–
carbon coupling constants (n J CH; n> 1) in small molecules is made. NMR experiments are …

Pure shift edited NMR methodologies for the extraction of Homo-and heteronuclear couplings with ultra-high resolution

SK Mishra, N Suryaprakash - Progress in Nuclear Magnetic Resonance …, 2023 - Elsevier
The scalar couplings that result in the splitting of the signals in the NMR spectrum arise due
to the interaction of the nuclear spins, whereby the spin polarization is transmitted through …

Speeding up the measurement of one-bond scalar (1J) and residual dipolar couplings (1D) by using non-uniform sampling (NUS)

CM Thiele, W Bermel - Journal of Magnetic Resonance, 2012 - Elsevier
The accurate and precise measurement of one-bond scalar and residual dipolar coupling
(RDC) constants is of prime importance to be able to use RDCs for structure determination. If …

Model free analysis of experimental residual dipolar couplings in small organic compounds

FA Roth, V Schmidts, J Rettig, CM Thiele - … Chemistry Chemical Physics, 2022 - pubs.rsc.org
Residual dipolar couplings (RDCs) contain information on the relative arrangement and
dynamics of internuclear spin vectors in chemical compounds. Classically, RDC data is …

Homonuclear BIRD-decoupled spectra for measuring one-bond couplings with highest resolution: CLIP/CLAP-RESET and constant-time-CLIP/CLAP-RESET

T Reinsperger, B Luy - Journal of Magnetic Resonance, 2014 - Elsevier
Heteronuclear one-bond couplings are of interest for various aspects of structural analysis of
small organic molecules, including for example the distinction of axial and equatorial …

Structural Discrimination in Small Molecules by Accurate Measurement of Long‐Range Proton–Carbon NMR Residual Dipolar Couplings

P Trigo‐Mouriño, A Navarro‐Vázquez… - Angewandte …, 2011 - Wiley Online Library
Although residual dipolar couplings (RDCs) are widely used in macromolecular structural
studies in relation to NMR spectroscopic experiments,[1] they are also proving to be very …

TITANIA: Model-free interpretation of residual dipolar couplings in the context of organic compounds

FA Roth, V Schmidts, CM Thiele - The Journal of Organic …, 2021 - ACS Publications
Residual dipolar couplings (RDCs) become increasingly important as additional NMR
parameters in the structure elucidation of organic compounds but are usually used in fitting …

PE HSQC: A simple experiment for simultaneous and sign-sensitive measurement of (1JCH+ DCH) and (2JHH+ DHH) couplings

P Tzvetkova, S Simova, B Luy - Journal of Magnetic Resonance, 2007 - Elsevier
The angular information content of residual dipolar couplings between nuclei of fixed
distance makes the accurate and sign-sensitive measurement of (1JCH+ DCH) and (2JHH+ …

High-resolution methods for the measurement of scalar coupling constants

Y Lin, Q Zeng, L Lin, Z Chen, PB Barker - Progress in Nuclear Magnetic …, 2018 - Elsevier
Scalar couplings provide important information regarding molecular structure and dynamics.
The measurement of scalar coupling constants constitutes a topic of interest and …

Recent advances in small molecule NMR: improved HSQC and HSQMBC experiments

L Castañar, T Parella - Annual Reports on NMR Spectroscopy, 2015 - Elsevier
A general description of the latest developments in heteronuclear single-quantum
correlation and heteronuclear single-quantum multiple bond correlation experiments …