Electrification of water: From basics to applications

Y Jin, C Wu, P Sun, M Wang, M Cui, C Zhang, Z Wang - Droplet, 2022 - Wiley Online Library
As the most common but indispensable matter to humankind, water usually stays in a
macroscopically electric neutral state. Due to its inherent molecular polarity, however, water …

Identifying reactive intermediates by mass spectrometry

J Mehara, J Roithová - Chemical Science, 2020 - pubs.rsc.org
Development of new reactions requires finding and understanding of novel reaction
pathways. In challenging reactions such as C–H activations, these pathways often involve …

Aqueous microdroplets enable abiotic synthesis and chain extension of unique peptide isomers from free amino acids

DT Holden, NM Morato… - Proceedings of the …, 2022 - National Acad Sciences
Amide bond formation, the essential condensation reaction underlying peptide synthesis, is
hindered in aqueous systems by the thermodynamic constraints associated with …

Atmospheric emission of nanoplastics from sewer pipe repairs

AC Morales, JM Tomlin, CP West… - Nature …, 2022 - nature.com
Nanoplastic particles are inadequately characterized environmental pollutants that have
adverse effects on aquatic and atmospheric systems, causing detrimental effects to human …

A critical analysis of electrospray techniques for the determination of accelerated rates and mechanisms of chemical reactions in droplets

G Rovelli, MI Jacobs, MD Willis, RJ Rapf… - Chemical …, 2020 - pubs.rsc.org
Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS)
have been widely used to report evidence that many chemical reactions in micro-and nano …

Spontaneous water radical cation oxidation at double bonds in microdroplets

L Qiu, NM Morato, KH Huang, RG Cooks - Frontiers in Chemistry, 2022 - frontiersin.org
Spontaneous oxidation of compounds containing diverse X= Y moieties (eg, sulfonamides,
ketones, esters, sulfones) occurs readily in organic-solvent microdroplets. This surprising …

Ultrafast enzymatic digestion of proteins by microdroplet mass spectrometry

X Zhong, H Chen, RN Zare - Nature communications, 2020 - nature.com
Enzymatic digestion for protein sequencing usually requires much time, and does not
always result in high sequence coverage. Here we report the use of aqueous microdroplets …

The role of analyte concentration in accelerated reaction rates in evaporating droplets

CJ Chen, ER Williams - Chemical science, 2023 - pubs.rsc.org
Accelerated reactions in microdroplets have been reported for a wide range of reactions with
some microdroplet reactions occurring over a million times faster than the same reaction in …

Surface-Area-to-Volume Ratio Determines Surface Tensions in Microscopic, Surfactant-Containing Droplets

A Bain, K Ghosh, NL Prisle, BR Bzdek - ACS Central Science, 2023 - ACS Publications
The surface composition of aerosol droplets is central to predicting cloud droplet number
concentrations, understanding atmospheric pollutant transformation, and interpreting …

Oxazolone mediated peptide chain extension and homochirality in aqueous microdroplets

L Qiu, RG Cooks - Proceedings of the National Academy of …, 2024 - National Acad Sciences
Peptide formation from amino acids is thermodynamically unfavorable but a recent study
provided evidence that the reaction occurs at the air/solution interfaces of aqueous …