Development of new reactions requires finding and understanding of novel reaction pathways. In challenging reactions such as C–H activations, these pathways often involve …
DT Holden, NM Morato… - Proceedings of the …, 2022 - National Acad Sciences
Amide bond formation, the essential condensation reaction underlying peptide synthesis, is hindered in aqueous systems by the thermodynamic constraints associated with …
Nanoplastic particles are inadequately characterized environmental pollutants that have adverse effects on aquatic and atmospheric systems, causing detrimental effects to human …
Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS) have been widely used to report evidence that many chemical reactions in micro-and nano …
Spontaneous oxidation of compounds containing diverse X= Y moieties (eg, sulfonamides, ketones, esters, sulfones) occurs readily in organic-solvent microdroplets. This surprising …
X Zhong, H Chen, RN Zare - Nature communications, 2020 - nature.com
Enzymatic digestion for protein sequencing usually requires much time, and does not always result in high sequence coverage. Here we report the use of aqueous microdroplets …
Accelerated reactions in microdroplets have been reported for a wide range of reactions with some microdroplet reactions occurring over a million times faster than the same reaction in …
The surface composition of aerosol droplets is central to predicting cloud droplet number concentrations, understanding atmospheric pollutant transformation, and interpreting …
L Qiu, RG Cooks - Proceedings of the National Academy of …, 2024 - National Acad Sciences
Peptide formation from amino acids is thermodynamically unfavorable but a recent study provided evidence that the reaction occurs at the air/solution interfaces of aqueous …