Metal‐ligand cooperation has emerged as a versatile tool for substrate activation in
chemical reactivity. Herein, we provide the synthesis and characterization of a monoboranyl …

Catalytic chemistry that involves the activation and transformation of main group substrates
is relatively undeveloped and current examples are generally mediated by expensive …

We report the synthesis of aromatic germanimines [(HMDS) 2Ge═ NAr](Ar= Ph, Mes, Dipp;
Mes= 2, 4, 6-Me3C6H2, Dipp= 2, 6-i Pr2C6H3) and an investigation into their associated …

Lewis acidic group 13 cations are useful mediators of small-molecule and catalytic reactivity
alike. Previous work has elaborated on the use of bulky β-diketiminate Al (III) cations for the …

Herein, by applying visible-light photoredox catalysis, we have now achieved the first
example of catalytic dehydrogenative coupling of phosphines and thiophenols that proceeds …

The incorporation of a PPC donor ligand set onto nickel is described. While C–H activation
routes using Ni (II) precursors and benzyl-and phenethyl-substituted diphosphines …

This chapter covers the literature published during 2016 relating to the synthesis, the
reactivity and the application of phosphines excluding the chemistry of their metal …

In a continuation to our earlier reports on the on-going developments in green synthetic
approaches in organophosphorus chemistry, 1 the present chapter is aimed at offering an …

The nickel (II) complex [κ3-BnPPC] NiBr (1), stabilized by an orthometalated-phosphine
benzyl group and two bulky phosphine donors, results in facile reductive elimination with …

N-Heterocyclic carbenes (NHC) are neutral, 2 electron donor ligands ubiquitous in modern
organometallic chemistry. Since the seminal report by Arduengo and co-workers of a stable …