[HTML][HTML] Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

AJ Carrod, V Gray, K Börjesson - Energy & Environmental Science, 2022 - pubs.rsc.org
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …

Anisotropic multiexciton quintet and triplet dynamics in singlet fission via pulsed electron spin resonance

TSC MacDonald, MJY Tayebjee… - Journal of the …, 2023 - ACS Publications
The quintet triplet-pair state may be generated upon singlet fission and is a critical
intermediate that dictates the fate of excitons, which can be exploited for photovoltaics …

Leveraging charge-transfer interactions in through-space-coupled pentacene dendritic oligomer for singlet exciton fission

J Kim, HT Teo, Y Hong, YC Liau, D Yim… - Journal of the …, 2023 - ACS Publications
Singlet exciton fission in organic chromophores has received much attention during the past
decade. Inspired by numerous spectroscopic studies in the solid state, there have been …

Employing Singlet Fission into Boosting the Generation of Singlet Oxygen and Superoxide Radicals for Photooxidation Reactions

T Wang, H Liu, X Wang, L Tang, J Zhou, X Song… - ACS …, 2023 - ACS Publications
Developing highly efficient heavy-metal-free photosensitizers (PSs) for the production of
reactive oxygen species (ROS) is urgent to achieve wide applications of ROS, yet it remains …

[HTML][HTML] Promoting multiexciton interactions in singlet fission and triplet fusion upconversion dendrimers

G He, EM Churchill, KR Parenti, J Zhang… - Nature …, 2023 - nature.com
Singlet fission and triplet-triplet annihilation upconversion are two multiexciton processes
intimately related to the dynamic interaction between one high-lying energy singlet and two …

Exploring Intermolecular Singlet Fission in Pyrene-Fused Azaacenes Film

Y Guo, M Feng, Z Zhang, S Ye, Y Wang… - Chemistry of …, 2023 - ACS Publications
Singlet fission (SF), a process that involves the conversion of one singlet exciton (S1) into a
pair of triplet excitons (T1), holds great technological promise for photovoltaics. Typical SF …

Thermodynamic control of intramolecular singlet fission and exciton transport in linear tetracene oligomers

S Nakamura, H Sakai, M Fuki, R Ooie… - Angewandte Chemie …, 2023 - Wiley Online Library
We newly synthesized a series of homo‐and hetero‐tetracene (Tc) oligomers to propose a
molecular design strategy for the efficient exciton transport in linear oligomers by promoting …

Direct exciton harvesting from a bound triplet pair

G He, KR Parenti, LM Campos, MY Sfeir - Advanced Materials, 2022 - Wiley Online Library
Singlet fission is commonly defined as the generation of two triplet excitons from a single
absorbed photon. However, ambiguities within this definition arise due to the complexity of …

[HTML][HTML] Robust singlet fission process in strong absorption π-expanded diketopyrrolopyrroles

L Wang, W Jiang, S Guo, S Wang, M Zhang, Z Liu… - Chemical …, 2022 - pubs.rsc.org
Singlet fission (SF) has drawn tremendous attention as a multiexciton generation process
that could mitigate the thermal loss and boost the efficiency of solar energy conversion …

Intramolecular Triplet Diffusion Facilitates Triplet Dissociation in a Pentacene Hexamer

PM Greißel, D Thiel, H Gotfredsen… - Angewandte Chemie …, 2024 - Wiley Online Library
Triplet dynamics in singlet fission depend strongly on the strength of the electronic coupling.
Covalent systems in solution offer precise control over such couplings. Nonetheless, efficient …