The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Chlorinated Solvents: Their Advantages, Disadvantages, and Alternatives in Organic and
Medicinal Chemistry | Chemical Reviews ACS ACS Publications C&EN CAS Find my …

A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

A main group-catalyzed method for the synthesis of aryl-and heteroarylamines by
intermolecular C–N coupling is reported. The method employs a small-ring …

A planar, trivalent phosphorus compound is shown to undergo reversible two-electron redox
cycling (PIII/PV) enabling its use as catalyst for a transfer hydrogenation reaction. The …

Experimental, spectroscopic, and computational studies are reported that provide an
evidence-based mechanistic description of an intermolecular reductive C–N coupling of …

Catalytic phosphorus (V)-mediated chlorination and bromination reactions of alcohols have
been developed. The new reactions constitute a catalytic version of the classical Appel …

A small-ring phosphacycloalkane (1, 2, 2, 3, 4, 4-hexamethylphosphetane, 3) catalyzes
intramolecular C–N bond forming heterocyclization of o-nitrobiaryl and-styrenyl derivatives …

A small-ring phosphacycle, 1, 2, 2, 3, 4, 4-hexamethylphosphetane, is found to catalyze
deoxygenative N–N bond-forming Cadogan heterocyclization of o-nitrobenzaldimines, o …

Several important reactions in organic chemistry thrive on stoichiometric formation of
phosphine oxides from phosphines. To avoid the resulting burden of waste and purification …