3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

A review on DBU-mediated organic transformations

SK Boddu, N Ur Rehman, TK Mohanta… - … Chemistry Letters and …, 2022 - Taylor & Francis
Diazabicyclo [5.4. 0] undec-7-ene (DBU) has received a significant importance in organic
synthesis during recent years because of its interesting ability to catalyze organic reaction …

Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction

Z Chen, Y Jiang, L Zhang, Y Guo… - Journal of the American …, 2019 - ACS Publications
A robust and practical protocol for preparing alkyl aryl ethers has been developed, which
relies on using two types of ligands to promote Cu-catalyzed alkoxylation of (hetero) aryl …

Key Mechanistic Features of the Silver (I)-Mediated Deconstructive Fluorination of Cyclic Amines: Multistate Reactivity versus Single-Electron Transfer

JB Roque, R Sarpong, DG Musaev - Journal of the American …, 2021 - ACS Publications
Density functional calculations have provided evidence that a Ag (I)-mediated
deconstructive fluorination of N-benzoylated cyclic amines (LH) with Selectfluor [(F …

Mechanism of the Palladium-Catalyzed C(sp3)–H Arylation of Aliphatic Amines: Unraveling the Crucial Role of Silver(I) Additives

W Feng, T Wang, D Liu, X Wang, Y Dang - ACS Catalysis, 2019 - ACS Publications
DFT calculations have been combined with experiments to study the mechanism of γ-C
(sp3)–H arylation of aliphatic amines promoted by palladium–glyoxylic acid cooperative …

Palladium-Catalyzed C2-Selective Direct Arylation of Benzo[b]thiophene 1,1-Dioxides with Arylboronic Acids

X Zhang, Y Lu, H Wang, M Chen, S Lin, X Huang - ACS omega, 2023 - ACS Publications
A novel oxidative cross-coupling of benzo [b] thiophene 1, 1-dioxides with arylboronic acids
was reported. The efficient reaction occurred at the C2-position via C–H activation, followed …

Ligand‐Free Copper‐Catalyzed Ullmann‐Type C− O Bond Formation in Non‐Innocent Deep Eutectic Solvents under Aerobic Conditions

AF Quivelli, M Marinò, P Vitale… - …, 2022 - Wiley Online Library
An efficient and novel protocol was developed for a Cu‐catalyzed Ullmann‐type aryl alkyl
ether synthesis by reacting various (hetero) aryl halides (Cl, Br, I) with alcohols as active …

Rh(III)-Catalyzed Oxidative C–2 Coupling of N-Pyridinylindoles with Benzo[b]thiophene 1,1-Dioxides via C–H Bond Activation

S Kumaran, K Parthasarathy - The Journal of Organic Chemistry, 2021 - ACS Publications
An efficient Rh (III)-catalyzed cross-dehydrogenative coupling of N-pyridinylindoles with
benzo [b] thiophene 1, 1-dioxides has been developed through directing-group-assisted C …

One-pot synthesis of dimerized arenes and heteroarenes under mild conditions using Co (I) as an active catalyst

A Pal, A Thakur - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
A feasible one-pot synthesis of dimerized arene and heteroarene systems was achieved by
employing 2 mol% of Co (II) catalyst 1 along with Zn dust at room temperature in 2–4 h. The …

Pd-NHC catalysed regioselective activation of B (3, 6)–H of o-carborane–a synergy between experiment and theory

JW Yu, CY Zhang, GA Chass, JX Zhang, WH Mu… - Dalton …, 2023 - pubs.rsc.org
Regioselective B–H activation of o-carboranes is an effective way for constructing o-
carborane derivatives, which have broad applications in medicine, catalysis and the wider …