Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …

This review covers the surface chemistry of porphyrins, phthalocyanines, their metal
complexes, and related compounds, with particular focus on chemical reactions at …

The chemical bond between an adsorbed, laterally coordinated metal ion and a metal
surface is affected by an additional axial ligand on the metal ion. This surface analogon of …

Nitroxyl (HNO) is the one-electron reduced and protonated congener of nitric oxide (• NO),
owning a distinct chemical profile. Based on real-time detection, we demonstrate that HNO is …

Recent studies distinguish the biological and pharmacological effects of nitroxyl (HNO) from
its oxidized/deprotonated product nitric oxide (· NO), but the lack of HNO detection methods …

Manganese porphyrins have been extensively investigated as model systems for the natural
enzyme cytochrome P450 and as synthetic oxidation catalysts. Here, we report single …

HNO (nitroxyl, azanone), joined the 'biologically relevant reactive nitrogen species' family in
the 2000s. Azanone is impossible to store due to its high reactivity and inherent low stability …

Nitroxyl or azanone (HNO) represents the redox-related (one electron reduced and
protonated) relative of the well-known biological signaling molecule nitric oxide (NO) …

The role of NO in biology is well established. However, an increasing body of evidence
suggests that azanone (HNO), could also be involved in biological processes, some of …

Azanone (HNO, nitroxyl) is a highly reactive and short-lived compound with intriguing and
highly relevant properties. It has been proposed to be a reaction intermediate in several …