Hierarchical materials as tailored nuclear waste forms: a perspective
HC zur Loye, T Besmann, J Amoroso… - Chemistry of …, 2018 - ACS Publications
This perspective focuses on the synthesis, characterization, and modeling of three classes of
hierarchical materials with potential for sequestering radionuclides: nanoparticles, porous …
hierarchical materials with potential for sequestering radionuclides: nanoparticles, porous …
Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides
This frontier article focuses on the use of flux crystal growth for the preparation of new
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
[HTML][HTML] Evolution of chernobyl corium in water: formation of secondary uranyl phases
VV Gurzhiy, BE Burakov, BY Zubekhina, AV Kasatkin - Materials, 2023 - mdpi.com
Two crystalline phases, which are analogues of common secondary uranyl minerals,
namely, becquerelite (Ca [(UO2) 6O4 (OH) 6]· 8H2O) and phurcalite (Ca2 [(UO2) 3O2 (PO4) …
namely, becquerelite (Ca [(UO2) 6O4 (OH) 6]· 8H2O) and phurcalite (Ca2 [(UO2) 3O2 (PO4) …
Overstepping Löwenstein's rule—A route to unique aluminophosphate frameworks with three-dimensional salt-inclusion and ion-exchange properties
The synthesis of four non-Löwenstein uranyl aluminophosphates,[Cs13Cl5][(UO2) 3Al2O
(PO4) 6], Rb7 [Al2O (PO4) 3][(UO2) 6O4 (PO4) 2], Cs3 [Al2O (PO4) 3][(UO2) 3O2], and Rb3 …
(PO4) 6], Rb7 [Al2O (PO4) 3][(UO2) 6O4 (PO4) 2], Cs3 [Al2O (PO4) 3][(UO2) 3O2], and Rb3 …
Observation of an Unusual Uranyl Cation–Cation Interaction in the Strongly Fluorescent Layered Uranyl Phosphates Rb6[(UO2)7O4(PO4)4] and Cs6[(UO2)7O4(PO4) …
Single crystals of two new uranyl phosphates, A6 [(UO2) 7O4 (PO4) 4](A= Cs, Rb), featuring
cation–cation interactions (CCIs) rarely observed in uranium (VI) compounds were …
cation–cation interactions (CCIs) rarely observed in uranium (VI) compounds were …
[HTML][HTML] Observation of the same new sheet topology in both the layered uranyl oxide-phosphate Cs11 [(UO2) 12 (PO4) 3O13] and the layered uranyl oxyfluoride …
Single crystals of four new layered uranyl phosphates, including three oxyfluoride-
phosphates, were synthesized by molten flux methods using alkali chloride melts, and their …
phosphates, were synthesized by molten flux methods using alkali chloride melts, and their …
Flux crystal growth of uranium (v) containing oxyfluoride perovskites
The novel phases Rb4NaU3O12− xFx (1), K4NaU3O12− xFx (2), and Rb2. 1K1. 9KU3O12−
xFx (3) were synthesized by molten flux methods using mixed alkali fluoride melts. The …
xFx (3) were synthesized by molten flux methods using mixed alkali fluoride melts. The …
Exploring the role of organic functional groups in the ionothermal synthesis of uranyl phosphate materials
TA Kohlgruber, DE Felton… - … für anorganische und …, 2022 - Wiley Online Library
Four new hybrid organic‐inorganic uranyl phosphate compounds were structurally
characterized after single crystals were grown via ionothermal synthesis using the ionic …
characterized after single crystals were grown via ionothermal synthesis using the ionic …
Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids
Single crystals of four new uranyl titanates have been grown via the flux growth method
using mixed alkali halide fluxes. Na2 (UO2)(TiO) O3 and KNa (UO2)(TiO) O3 have …
using mixed alkali halide fluxes. Na2 (UO2)(TiO) O3 and KNa (UO2)(TiO) O3 have …
Investigation of phase equilibria in SrO–La2O3–P2O5 system and thermo physical properties of established compounds
Sub solidus phase relations in pseudo ternary SrO–La 2 O 3–P 2 O 5 system were
determined experimentally at 1523 K in air. To confirm the formation of phases at this …
determined experimentally at 1523 K in air. To confirm the formation of phases at this …