MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Bimetallic metal–organic frameworks and their derivatives

L Chen, HF Wang, C Li, Q Xu - Chemical science, 2020 - pubs.rsc.org
Bimetallic metal–organic frameworks (MOFs) have two different metal ions in the inorganic
nodes. According to the metal distribution, the architecture of bimetallic MOFs can be …

Electronic state and microenvironment modulation of metal nanoparticles stabilized by MOFs for boosting electrocatalytic nitrogen reduction

L Wen, K Sun, X Liu, W Yang, L Li… - Advanced …, 2023 - Wiley Online Library
Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …

Charge separation by creating band bending in metal–organic frameworks for improved photocatalytic hydrogen evolution

C Zhang, C Xie, Y Gao, X Tao, C Ding… - Angewandte …, 2022 - Wiley Online Library
Metal–organic frameworks (MOFs) have been intensively studied as a class of
semiconductor‐like materials in photocatalysis. However, band bending, which plays a …

Locking effect in metal@ MOF with superior stability for highly chemoselective catalysis

Y Zhong, P Liao, J Kang, Q Liu, S Wang… - Journal of the …, 2023 - ACS Publications
Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis
but are prone to reunion and loss during the catalytic process, resulting in low …

Interfacial microenvironment modulation boosting electron transfer between metal nanoparticles and MOFs for enhanced photocatalysis

M Xu, D Li, K Sun, L Jiao, C Xie, C Ding… - Angewandte …, 2021 - Wiley Online Library
Interfacial electron transfer between cocatalyst and photosensitizer is key in heterogeneous
photocatalysis, yet the underlying mechanism remains subtle and unclear. Surfactant coated …

Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis

Q Yang, Q Xu, HL Jiang - Chemical Society Reviews, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs), established as a relatively new class of crystalline
porous materials with high surface area, structural diversity, and tailorability, attract …

Recent development of metal-organic framework nanocomposites for biomedical applications

X Ge, R Wong, A Anisa, S Ma - Biomaterials, 2022 - Elsevier
Albeit metal-organic framework (MOF) composites have been extensively explored,
reducing the size and dimensions of various contents within the composition, to the …

Single Pt atoms confined into a metal–organic framework for efficient photocatalysis

X Fang, Q Shang, Y Wang, L Jiao, T Yao… - Advanced …, 2018 - Wiley Online Library
It is highly desirable yet remains challenging to improve the dispersion and usage of noble
metal cocatalysts, beneficial to charge transfer in photocatalysis. Herein, for the first time …

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

J Liu, J Huang, L Zhang, J Lei - Chemical Society Reviews, 2021 - pubs.rsc.org
Metal–organic frameworks (MOFs) are an emerging class of molecular crystalline materials
built from metal ions or clusters bridged by organic linkers. By taking advantage of their …