Photons, Excitons, and Electrons in Covalent Organic Frameworks

D Blätte, F Ortmann, T Bein - Journal of the American Chemical …, 2024 - ACS Publications
Covalent organic frameworks (COFs) are created by the condensation of molecular building
blocks and nodes to form two-dimensional (2D) or three-dimensional (3D) crystalline …

Structure evolution of 2D covalent organic frameworks unveiled by single-crystal X-ray diffraction

L Yi, Y Gao, S Luo, T Wang, H Deng - Journal of the American …, 2024 - ACS Publications
We report 9 crystal structures of a two-dimensional (2D) covalent organic framework (COF),
including the parent Py-1P, 5 derivatives formed by chemical reactions, and 3 dynamic …

Computational Modeling of Reticular Materials: The Past, the Present, and the Future

W Temmerman, R Goeminne, KS Rawat… - Advanced …, 2024 - Wiley Online Library
Reticular materials rely on a unique building concept where inorganic and organic building
units are stitched together giving access to an almost limitless number of structured ordered …

S‐Scheme Heterojunction Fabricated from Covalent Organic Framework and Quantum Dot for Enhanced Photosynthesis of Hydrogen Peroxide from Water and Air

X Ma, S Li, Y Gao, N Li, Y Han, H Pan… - Advanced Functional …, 2024 - Wiley Online Library
Covalent organic frameworks (COFs) with stable crystalline porous structures and flexible
assembly properties contribute to the direct photocatalytic synthesis of H2O2 to meet the …

Integration of Perylene Diimide into a Covalent Organic Framework for Photocatalytic Oxidation

Z Li, J Jiao, W Fu, K Gao, X Peng… - Angewandte Chemie …, 2024 - Wiley Online Library
Perylene diimides (PDIs) have garnered considerable attention due to their immense
potential in photocatalysis. However, manipulating the molecular packing within their …

Structure regulation of 2D materials by atom confinement for electrocatalysis

Z Liu, L Fu, J Liu, M Wang, J Zhou - Coordination Chemistry Reviews, 2024 - Elsevier
Developing highly active and stable electrocatalysts is significant for generating green
energy. Ultrahigh exposed active atoms, tunable electronic properties, and high charge …

Azatriangulene‐Based Conductive C═ C Linked Covalent Organic Frameworks with Near‐Infrared Emission

E Hamzehpoor, P Ghamari, Y Tao… - Advanced …, 2024 - Wiley Online Library
Two near‐infrared (NIR) emissive π‐conjugated covalent organic frameworks (COFs)
pTANG1 and pTANG2 are synthesized using Knoevenagel condensation of …

2.5-dimensional covalent organic frameworks

T Kitano, S Goto, X Wang, T Kamihara, Y Sei… - Nature …, 2025 - nature.com
Covalently bonded crystalline substances with micropores have broad applications.
Covalent organic frameworks (COFs) are representative of such substances. They have so …

Single-Crystal Dynamic Covalent Organic Frameworks for Adaptive Guest Alignments

S Liu, L Wei, T Zeng, W Jiang, Y Qiu… - Journal of the …, 2024 - ACS Publications
Dynamic 3D covalent organic frameworks (COFs) have shown a concerted structural
transformation upon adaptive guest inclusion. However, the origin of the conformational …

[HTML][HTML] Recent Advances in the Utilization of Chiral Covalent Organic Frameworks for Asymmetric Photocatalysis

P Liu, W Dai, X Shen, X Shen, Y Zhao, JJ Liu - Molecules, 2024 - mdpi.com
The use of light energy to drive asymmetric organic transformations to produce high-value-
added organic compounds is attracting increasing interest as a sustainable strategy for …