Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Polyoxometalates (POMs): from electroactive clusters to energy materials

MR Horn, A Singh, S Alomari… - Energy & …, 2021 - pubs.rsc.org
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …

Recent advances in polyoxometalate-catalyzed reactions

SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

Polyoxometalate‐soft matter composite materials: design strategies, applications, and future directions

JH Kruse, M Langer, I Romanenko… - Advanced functional …, 2022 - Wiley Online Library
Molecular metal oxides or polyoxometalates (POMs) offer unrivaled properties in areas
ranging from catalysis and energy conversion through to molecular electronics, biomimetics …

Molecular chromophore–catalyst assemblies for solar fuel applications

DL Ashford, MK Gish, AK Vannucci… - Chemical …, 2015 - ACS Publications
As the world's population increases, the US Department of Energy has estimated that energy
consumption will increase with it, increasing from 5.7× 1020 J in 2012 to 8.1× 1020 J in …

Computational electrochemistry: prediction of liquid-phase reduction potentials

AV Marenich, J Ho, ML Coote, CJ Cramer… - Physical Chemistry …, 2014 - pubs.rsc.org
This article reviews recent developments and applications in the area of computational
electrochemistry. Our focus is on predicting the reduction potentials of electron transfer and …

Polyoxometalate-based cobalt–phosphate molecular catalysts for visible light-driven water oxidation

XB Han, ZM Zhang, T Zhang, YG Li, W Lin… - Journal of the …, 2014 - ACS Publications
A series of all-inorganic, abundant-metal-based, high-nuclearity cobalt–phosphate (Co–Pi)
molecular catalysts [{Co4 (OH) 3 (PO4)} 4 (SiW9O34) 4] 32–(1),[{Co4 (OH) 3 (PO4)} 4 …

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

T Ma, R Yan, X Wu, M Wang, B Yin, S Li… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

The reactivity and stability of polyoxometalate water oxidation electrocatalysts

D Gao, I Trentin, L Schwiedrzik, L González, C Streb - Molecules, 2019 - mdpi.com
This review describes major advances in the use of functionalized molecular metal oxides
(polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions …

Quantum chemical modeling of homogeneous water oxidation catalysis

RZ Liao, PEM Siegbahn - ChemSusChem, 2017 - Wiley Online Library
The design of efficient and robust water oxidation catalysts has proven challenging in the
development of artificial photosynthetic systems for solar energy harnessing and storage …