The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

As one of the most critical approaches to resolve the energy crisis and environmental
concerns, carbon dioxide (CO2) photoreduction into value‐added chemicals and solar fuels …

The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

The problem with current state-of-the-art catalysts for CO2 photo-or electroreduction is
rooted in the notion that no single system can independently control, and thus optimize, the …

The electrochemical reduction of CO2 into useful fuels and chemical feedstocks offers great
promise for conversion to a carbon-neutral economy. However, challenges in product …

The electronic character of porphyrin active sites for electrocatalytic reduction of CO2 to CO
in a two-dimensional covalent organic framework (COF) was tuned by modification of the …

Polypyridyl transition metal complexes represent one of the more thoroughly studied classes
of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with …

Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

The replacement of fossil fuels by a clean and renewable energy source is one of the most
urgent and challenging issues our society is facing today, which is why intense research has …

Proton-coupled electron transfer (PCET) is ubiquitous throughout chemistry and biology.
This Perspective discusses recent advances and current challenges in the field of PCET …