On the Edge of the Known: Extremely Electron‐Rich (Di) Carboranyl Phosphines
J Schulz, R Clauss, A Kazimir… - Angewandte Chemie …, 2023 - Wiley Online Library
The syntheses of the first B9‐connected carboranylphosphines (B9‐Phos) featuring two
carboranyl moieties as well as access to B9‐Phos ligands with bulky electron‐donating …
carboranyl moieties as well as access to B9‐Phos ligands with bulky electron‐donating …
Diazo Decomposition and Carbene Transfer Mediated by a Pincer Gold (III) Complex
R Wei, L Ma, S Mallet-Ladeira, D Bourissou - Organometallics, 2024 - ACS Publications
The pincer triflimide Au (III) complex (N∧ C∧ C) AuNTf2 2 is shown to decompose aryl
diazo compounds Ph2CN2,(Dmp) CN2H (Dmp= 2, 6-dimesitylphenyl), and (p-F3CPh) …
diazo compounds Ph2CN2,(Dmp) CN2H (Dmp= 2, 6-dimesitylphenyl), and (p-F3CPh) …
A Convergent, Modular Approach to Trifluoromethyl‐Bearing 5‐Membered Rings via Catalytic C(sp3)−H Activation
K Wu, X Zhang, LL Wu, JS Huang… - Angewandte Chemie …, 2023 - Wiley Online Library
Trifluoromethyl‐bearing 5‐membered rings are prevalent in bioactive molecules, but
modular approaches to these compounds by functionalization of robust C (sp3)− H bonds in …
modular approaches to these compounds by functionalization of robust C (sp3)− H bonds in …
A Cavity-Shaped Gold(I) Fragment Enables CO2 Insertion into Au–OH and Au–NH Bonds
A cavity-shaped linear gold (I) hydroxide complex acts as a platform to access unusual gold
monomeric species. Notably, this sterically crowded gold fragment enables the trapping of …
monomeric species. Notably, this sterically crowded gold fragment enables the trapping of …
Synthesis of gem‐Difluorocyclobutane‐Fused Indolines via Ruthenium‐Catalyzed Defluorinative Annulation of Trifluoromethyl Carbenoids with 2‐Alkenylanilines
H Tan, H Li, S Wu, A Abdukader… - Advanced Synthesis & …, 2024 - Wiley Online Library
A ruthenium‐catalyzed defluorinative annulation of 2‐alkenylanilines with α‐trifluoromethyl
diazoester or diazoketones is described. The reaction has broad substrate scope, affording …
diazoester or diazoketones is described. The reaction has broad substrate scope, affording …
Combining ligand-enhanced backdonation and steric shielding to stabilize a mono-substituted Au (i) carbene
D Vesseur, K Miqueu, D Bourissou - Chemical Communications, 2023 - pubs.rsc.org
A mono-substituted Au (I) carbene was prepared by reacting HC (N2)(Dmp)(Dmp= 2, 6-
dimesitylphenyl) with an (o-carboranyl)-diphosphine AuNTf2 complex. It is stable up to− 10° …
dimesitylphenyl) with an (o-carboranyl)-diphosphine AuNTf2 complex. It is stable up to− 10° …
Am Rande des Bekannten: Extrem elektronenreiche (Di) carboranylphosphane
J Schulz, R Clauss, A Kazimir, S Holzknecht… - Angewandte …, 2023 - Wiley Online Library
Die Synthese der ersten B9‐verbundenen Carboranylphosphane (B9‐Phos) mit zwei
Carboranyleinheiten sowie der Zugang zu B9‐Phos‐Liganden mit sperrigen elektronen …
Carboranyleinheiten sowie der Zugang zu B9‐Phos‐Liganden mit sperrigen elektronen …