Enantioenriched organoboron intermediates are important building blocks in organic
synthesis and drug discovery. Recently, transition metal-catalyzed enantioselective 1, 2 …

This tutorial review describes recent developments in carbon–nitrogen bond-forming
reactions (amination, amidation, nitration and nitrosation) that involve the use of boronic …

Catalytic asymmetric multicomponent 1, 2-boronate rearrangements provide a practical
approach for synthesizing highly valuable enantioenriched boronic esters. When applied to …

The structural diversity of sp3‐triorganometallic reagents enhances their potentiality in the
modular construction of molecular complexity in chemical synthesis. Despite significant …

The electrophilic fluorination of geminal alkyl substituted vinyl‐Bmida derivatives proceeds
via bora‐Wagner–Meerwein rearrangement. According to DFT modelling studies this …

Methods for the fluorination of organoboron compounds are described. This review will
cover the fluorination of aromatic and aliphatic systems using both electrophilic and …

We have developed a convergent method for the synthesis of allylic alcohols that involves a
reductive coupling of terminal alkynes with α-chloro boronic esters. The new method affords …

Tetracoordinate boron species have emerged as radical precursors via deboronation by
photo-induced single electron transfer (SET) pathway. These reactions usually produce an …

The broad synthetic utility of organoboron compounds stems from their ready ability to
undergo 1, 2-migrations. Normally, such shifts are induced by α-leaving groups or by …

Multisubstituted allylic boronates are attractive and valuable precursors for the rapid and
stereoselective construction of densely substituted carbon skeletons. Herein, we report the …