Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

A catalytic system for intermolecular benzylic C (sp3)–H amination is developed utilizing 1,
2, 3, 4-tetrazole as a nitrene precursor via iron catalysis. This method enables direct …

The ability to selectively functionalize ubiquitous C–H bonds streamlines the construction of
complex molecular architectures from easily available precursors. Here we report enzyme …

Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …

Control of enantioselectivity remains a major challenge in radical chemistry. The emergence
of metalloradical catalysis (MRC) offers a conceptually new strategy for addressing this and …

A Cu-catalyzed strategy has been developed that harnesses a radical relay mechanism to
intercept a distal C-centered radical for C–C bond formation. This approach enables …

A concept for intramolecular denitrogenative C (sp3)–H amination of 1, 2, 3, 4-tetrazoles
bearing unactivated primary, secondary, and tertiary C–H bonds is discovered. This catalytic …