Review of Fe-based spin crossover metal complexes in multiscale device architectures
N Amin, SM Said, MFM Salleh, AM Afifi, N Ibrahim… - Inorganica Chimica …, 2023 - Elsevier
Metal complexes involving d 4-d 7 first-row transition metals exhibit spin-crossover (SCO)
behaviour between low-spin and high-spin states in response to external stimuli such as …
behaviour between low-spin and high-spin states in response to external stimuli such as …
Optimised thermally driven molecular stability of an SCO metal complex for TEC Seebeck generation enhancement
The thermoelectricity effect allows the generation of electrical potential in an electrolyte upon
application of a thermal gradient. In the previous work, the spin crossover effect in metal …
application of a thermal gradient. In the previous work, the spin crossover effect in metal …
Thermo-electrochemical generation capabilities of octahedral spin crossover complexes of Mn (II), Fe (II) and Co (II) with N-donor ligands and benzoate counter ion
MMIM Hasnan, N Abdullah, SM Said, MFM Salleh… - Electrochimica …, 2018 - Elsevier
Spin crossover ionic complexes have shown potential as efficient thermoelectrochemical
materials which are capable of converting electrochemical energy into electrical potential in …
materials which are capable of converting electrochemical energy into electrical potential in …
Comparative analysis between solution-phase and thin films of cobalt (II) spin crossover (SCO) complexes with 8, 10, 12-carbon alkyl chains based on structural …
NAAM Amin, SM Said, NMJN Ibrahim… - Journal of Materials …, 2024 - Springer
Spin crossover (SCO) materials are compounds capable of switching between high-spin
and low-spin states in response to external stimuli such as temperature. In this work, a series …
and low-spin states in response to external stimuli such as temperature. In this work, a series …
Ultra-high Seebeck coefficient of a thermal sensor through entropic optimisation of ligand length of Fe (ii) spin-crossover (SCO) materials
HC Hassan, SM Said, NMJN Ibrahim, MMIM Hasnan… - RSC …, 2021 - pubs.rsc.org
In this work, we present a spin-crossover (SCO) complex molecular formulation [Fe (Ln)
2](BF4) 2 in an electrochemical single couple solution. A Seebeck voltage arises when an …
2](BF4) 2 in an electrochemical single couple solution. A Seebeck voltage arises when an …
Optimisation of octahedral iron (II) and cobalt (II) spin-crossover metal complex for thermoelectric application
Four spin-crossover (SCO) complexes with general formulae,[M 2 (CH 3 COO) 4 (L) 2] and
[M (L) 3](BF 4) 2, where M= Fe (II) and Co (II), containing extended π-conjugated bipyridyl …
[M (L) 3](BF 4) 2, where M= Fe (II) and Co (II), containing extended π-conjugated bipyridyl …
Effect of PMMA additive on thin film morphology and charge storage in Fe (II) spin-crossover complexes
NAA Mohd Amin, S Mohd Said… - … Crystals and Liquid …, 2024 - Taylor & Francis
This study explores two Fe (II) spin-crossover (SCO) complexes; mononuclear ionic [Fe
(LC12) 3](BF4) 2](Fe-mono) and dinuclear molecular [Fe2 (CH3COO) 4 (LC12) 2](Fe-dinuc) …
(LC12) 3](BF4) 2](Fe-mono) and dinuclear molecular [Fe2 (CH3COO) 4 (LC12) 2](Fe-dinuc) …
Complexes of nickel (II) carboxylates with pyridine and cyclam: crystal structures, mesomorphisms, and thermoelectrical properties
N Abdullah, S Mohd Said, YY Halid… - Journal of …, 2016 - Taylor & Francis
Abstract Nickel (II) carboxylates [Ni (CH3 (CH2) 14COO) 2 (H2O) 2](1) and [Ni (C6H5COO) 2
(H2O) 2](2) were obtained from reactions of NiCl2· 6H2O with CH3 (CH2) 14COONa and …
(H2O) 2](2) were obtained from reactions of NiCl2· 6H2O with CH3 (CH2) 14COONa and …
Systematic correlation between ligand length, bandgap energy and Seebeck voltage of Fe-based spincrossover (SCO) metal complexes through optical …
Fe-based spincrossover (SCO) molecular complexes have shown to exhibit spincrossover
behavior when subjected to stimuli such as heat, light and pressure. In a previous work …
behavior when subjected to stimuli such as heat, light and pressure. In a previous work …
Investigation of iron (III) ionic structural complexes for seebeck coefficient enhancement using variation of ligand lengths with extended Π-conjugated bipyridyl ligands
Five new octahedral spin-crossover magnetic complexes with general formulae,[Fe (LCn)
3](BF 4) 3, where L= ligand, and n= 8, 10, 12, 14, 16, were synthesized and characterized …
3](BF 4) 3, where L= ligand, and n= 8, 10, 12, 14, 16, were synthesized and characterized …